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Titles listThe hydrophobic effect as a driving force in the self-assembly of a [2 x 2] copper(I) grid
Titles listThe hydrophobic effect as a driving force in the self-assembly of a [2 x 2] copper(I) grid
Scientific Article
unige:6979 
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The hydrophobic effect as a driving force in the self-assembly of a [2 x 2] copper(I) grid |
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| Published in | Angewandte Chemie: International Edition. 2004, vol. 43, no. 48, p. 6724-6727 | |
| Abstract | Spring-loaded supramolecular chemistry: Pyridine-2-carboxaldehyde reacts with the m-phenylenediamine shown in aqueous solution in the presence of CuI ions to give a tetracopper(I) grid complex (see structure). This structure is stable in water, but not in any of the organic solvents tried. The strain incorporated into the structure is compensated by a diffuse pressure applied by the hydrophobic effect. R=2-hydroxyethylcarbamoyl. | |
| Keywords | Copper — Dynamic combinatorial chemistry — Chiff bases — Self-assembly — Template synthesis | |
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| Citation (ISO format) | NITSCHKE, Jonathan, HUTIN, Marie, BERNARDINELLI, Gérald Hugues. The hydrophobic effect as a driving force in the self-assembly of a [2 x 2] copper(I) grid. In: Angewandte Chemie: International Edition, 2004, vol. 43, n° 48, p. 6724-6727. doi: 10.1002/anie.200461308 https://archive-ouverte.unige.ch/unige:6979 |
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