Mutual stabilization between imine ligands and copper(I) ions in aqueous solution

Nitschke, Jonathan

doi:10.1002/anie.200454082

Scientific article

English

Mutual stabilization between imine ligands and copper(I) ions in aqueous solution

Contributors

Nitschke, Jonathan

Published in

Angewandte Chemie, vol. 43, no. 23, p. 3073-3075

Publication date

2004

Abstract

Chemical symbiosis enables the quantitative formation of CuI-imine complexes from the mixture of Schiff base precursors with CuII and Cu0 in water (see scheme), even though neither CuI nor imines are ordinarily stable in aqueous solution. The imine ligands undergo selective exchange with free amines, and the complex forms readily in the presence of a dynamic combinatorial library of nonchelating aldehydes.

Keywords

Combinatorial chemistry
Copper
Schiff bases
Supramolecular chemistry
Template synthesis

UNIGE affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

NITSCHKE, Jonathan. Mutual stabilization between imine ligands and copper(I) ions in aqueous solution. In: Angewandte Chemie, 2004, vol. 43, n° 23, p. 3073–3075. doi: 10.1002/anie.200454082

Article

Identifiers

PID : unige:6977
DOI : 10.1002/anie.200454082

Journal ISSN

1433-7851

701views

0downloads

Creation

18/06/2010 08:54:51

First validation

18/06/2010 08:54:51

Update

14/03/2023 15:30:32

Status update

14/03/2023 15:30:31

Last indexation

10/06/2025 21:33:51

Mutual stabilization between imine ligands and copper(I) ions in aqueous solution

Contributors

Published in

Publication date

Abstract

Keywords

UNIGE affiliation entities

Citation (ISO format)

Main files (1)

Identifiers

Journal ISSN

Technical informations

Creation

First validation

Update

Status update

Last indexation