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Scientific article
English

Ion-Pair Mediated Asymmetric Synthesis of a Configurationally Stable Mononuclear Tris(diimine) Iron(II) Complex

Published inAngewandte Chemie, vol. 41, no. 13, p. 2317-2319
Publication date2002
Abstract

Configurational stability is conferred on the complex 1 (R=4-MeOC6H4) by the carefully designed tetradentate bis(1,10-phenanthroline) ligand. The resolution and asymmetric synthesis of 1 were readily achieved by using tris(tetrachlorobenzenediolato)phosphate(V) anions (2) as chiral auxiliaries. The picture shows the separation of the enantiomers of 1 by preparative ion-pair thin-layer chromatography.

Keywords
  • Chiral auxiliaries
  • Chiral resolution
  • Ion pairs
  • Iron
  • N ligands
Citation (ISO format)
MONCHAUD, David et al. Ion-Pair Mediated Asymmetric Synthesis of a Configurationally Stable Mononuclear Tris(diimine) Iron(II) Complex. In: Angewandte Chemie, 2002, vol. 41, n° 13, p. 2317–2319. doi: 10.1002/1521-3773(20020703)41:13%3C2317::AID-ANIE2317%3E3.0.CO;2-W
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ISSN of the journal1433-7851
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