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Title

Ion-Pair Mediated Asymmetric Synthesis of a Configurationally Stable Mononuclear Tris(diimine) Iron(II) Complex

Authors
Pomeranc, Didier
Heitz, Valérie
Chambron, Jean-Claude
Sauvage, Jean-Pierre
Published in Angewandte Chemie: International Edition. 2002, vol. 41, no. 13, p. 2317-2319
Abstract Configurational stability is conferred on the complex 1 (R=4-MeOC6H4) by the carefully designed tetradentate bis(1,10-phenanthroline) ligand. The resolution and asymmetric synthesis of 1 were readily achieved by using tris(tetrachlorobenzenediolato)phosphate(V) anions (2) as chiral auxiliaries. The picture shows the separation of the enantiomers of 1 by preparative ion-pair thin-layer chromatography.
Keywords Chiral auxiliariesChiral resolutionIon pairsIronN ligands
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MONCHAUD, David et al. Ion-Pair Mediated Asymmetric Synthesis of a Configurationally Stable Mononuclear Tris(diimine) Iron(II) Complex. In: Angewandte Chemie: International Edition, 2002, vol. 41, n° 13, p. 2317-2319. https://archive-ouverte.unige.ch/unige:6975

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Deposited on : 2010-06-18

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