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Title

Synthesis and Resolution of the Configurationally Stable Tris(tetrachlorobenzenediolato)phosphate Anion

Authors
Ginglinger, Catherine
Published in Angewandte Chemie. International edition in English. 1997, vol. 36, no. 6, p. 608-610
Abstract Easily accessible and configurationally stable are words that describe the enantiopure tris(tetrachlorobenzenediolato)phosphate(V) ion (1). These qualities predetermine 1 for use in enantiomeric resolution and asymmetric synthesis. X-ray structure analysis of the cinchonidinium salt of 1 confirmed the octahedral geometry and provided the absolute configuration of the anion.
Keywords ChiralityCinchonidineEnantiomeric resolutionPhosphorus
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Note Paru également dans Angewandte Chemie sous le titre:"Synthese und Trennung der Enantiomere des konfigurationsstabilen Tris(tetrachlorbenzoldiolato)phosphat(V)-Ions" en 1997, 109(6), 660-662
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LACOUR, Jérôme et al. Synthesis and Resolution of the Configurationally Stable Tris(tetrachlorobenzenediolato)phosphate Anion. In: Angewandte Chemie. International edition in English, 1997, vol. 36, n° 6, p. 608-610. doi: 10.1002/anie.199706081 https://archive-ouverte.unige.ch/unige:6974

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Deposited on : 2010-06-18

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