Synthesis and Resolution of the Configurationally Stable Tris(tetrachlorobenzenediolato)phosphate Anion

Lacour, Jérôme; Ginglinger, Catherine; Grivet, Chantal; Bernardinelli, Gérald Hugues

doi:10.1002/anie.199706081

Scientific article

English

Synthesis and Resolution of the Configurationally Stable Tris(tetrachlorobenzenediolato)phosphate Anion

ContributorsLacour, Jérôme

; Ginglinger, Catherine; Grivet, Chantal; Bernardinelli, Gérald Hugues

Published inAngewandte Chemie. International edition in English, vol. 36, no. 6, p. 608-610

Publication date1997

Abstract

Easily accessible and configurationally stable are words that describe the enantiopure tris(tetrachlorobenzenediolato)phosphate(V) ion (1). These qualities predetermine 1 for use in enantiomeric resolution and asymmetric synthesis. X-ray structure analysis of the cinchonidinium salt of 1 confirmed the octahedral geometry and provided the absolute configuration of the anion.

Keywords

Chirality
Cinchonidine
Enantiomeric resolution
Phosphorus

NoteParu également dans Angewandte Chemie sous le titre:"Synthese und Trennung der Enantiomere des konfigurationsstabilen Tris(tetrachlorbenzoldiolato)phosphat(V)-Ions" en 1997, 109(6), 660-662

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

LACOUR, Jérôme et al. Synthesis and Resolution of the Configurationally Stable Tris(tetrachlorobenzenediolato)phosphate Anion. In: Angewandte Chemie. International edition in English, 1997, vol. 36, n° 6, p. 608–610. doi: 10.1002/anie.199706081

Article

Identifiers

PID : unige:6974
DOI : 10.1002/anie.199706081

Journal ISSN0570-0833

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Synthesis and Resolution of the Configurationally Stable Tris(tetrachlorobenzenediolato)phosphate Anion

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