Synthesis and Resolution of the Configurationally Stable Tris(tetrachlorobenzenediolato)phosphate Anion

Browse by...

Deposit

Highlights

More informations

Title		Synthesis and Resolution of the Configurationally Stable Tris(tetrachlorobenzenediolato)phosphate Anion
Authors		Lacour, Jérôme Ginglinger, Catherine Grivet, Chantal Bernardinelli, Gérald Hugues
Published in		Angewandte Chemie: International Edition in English. 1997, vol. 36, no. 6, p. 608-610
Abstract		Easily accessible and configurationally stable are words that describe the enantiopure tris(tetrachlorobenzenediolato)phosphate(V) ion (1). These qualities predetermine 1 for use in enantiomeric resolution and asymmetric synthesis. X-ray structure analysis of the cinchonidinium salt of 1 confirmed the octahedral geometry and provided the absolute configuration of the anion.
Keywords		Chirality — Cinchonidine — Enantiomeric resolution — Phosphorus
Identifiers		DOI: 10.1002/anie.199706081
Note		Paru également dans Angewandte Chemie sous le titre:"Synthese und Trennung der Enantiomere des konfigurationsstabilen Tris(tetrachlorbenzoldiolato)phosphat(V)-Ions" en 1997, 109(6), 660-662
Full text		Article - Limited access to UNIGE
Structures		Faculté des sciences / Section de chimie et biochimie / Département de chimie organique
Citation (ISO format)		LACOUR, Jérôme et al. Synthesis and Resolution of the Configurationally Stable Tris(tetrachlorobenzenediolato)phosphate Anion. In: Angewandte Chemie: International Edition in English, 1997, vol. 36, n° 6, p. 608-610. doi: 10.1002/anie.199706081 https://archive-ouverte.unige.ch/unige:6974