Synthesis and Resolution of the Configurationally Stable Tris(tetrachlorobenzenediolato)phosphate Anion

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Title		Synthesis and Resolution of the Configurationally Stable Tris(tetrachlorobenzenediolato)phosphate Anion
Authors		Lacour, Jérôme Ginglinger, Catherine Grivet, Chantal Bernardinelli, Gérald Hugues
Published in		Angewandte Chemie: International Edition in English. 1997, vol. 36, no. 6, p. 608-610
Abstract		Easily accessible and configurationally stable are words that describe the enantiopure tris(tetrachlorobenzenediolato)phosphate(V) ion (1). These qualities predetermine 1 for use in enantiomeric resolution and asymmetric synthesis. X-ray structure analysis of the cinchonidinium salt of 1 confirmed the octahedral geometry and provided the absolute configuration of the anion.
Keywords		Chirality — Cinchonidine — Enantiomeric resolution — Phosphorus
Identifiers		DOI: 10.1002/anie.199706081
Note		Paru également dans Angewandte Chemie sous le titre:"Synthese und Trennung der Enantiomere des konfigurationsstabilen Tris(tetrachlorbenzoldiolato)phosphat(V)-Ions" en 1997, 109(6), 660-662
Full text		Article - Limited access to UNIGE
Structures		Faculté des sciences / Section de chimie et biochimie / Département de chimie organique
Citation (ISO format)		LACOUR, Jérôme et al. Synthesis and Resolution of the Configurationally Stable Tris(tetrachlorobenzenediolato)phosphate Anion. In: Angewandte Chemie: International Edition in English, 1997, vol. 36, n° 6, p. 608-610. https://archive-ouverte.unige.ch/unige:6974