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Scientific article
English

Synthesis and Resolution of the Configurationally Stable Tris(tetrachlorobenzenediolato)phosphate Anion

Published inAngewandte Chemie. International edition in English, vol. 36, no. 6, p. 608-610
Publication date1997
Abstract

Easily accessible and configurationally stable are words that describe the enantiopure tris(tetrachlorobenzenediolato)phosphate(V) ion (1). These qualities predetermine 1 for use in enantiomeric resolution and asymmetric synthesis. X-ray structure analysis of the cinchonidinium salt of 1 confirmed the octahedral geometry and provided the absolute configuration of the anion.

Keywords
  • Chirality
  • Cinchonidine
  • Enantiomeric resolution
  • Phosphorus
NoteParu également dans Angewandte Chemie sous le titre:"Synthese und Trennung der Enantiomere des konfigurationsstabilen Tris(tetrachlorbenzoldiolato)phosphat(V)-Ions" en 1997, 109(6), 660-662
Citation (ISO format)
LACOUR, Jérôme et al. Synthesis and Resolution of the Configurationally Stable Tris(tetrachlorobenzenediolato)phosphate Anion. In: Angewandte Chemie. International edition in English, 1997, vol. 36, n° 6, p. 608–610. doi: 10.1002/anie.199706081
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ISSN of the journal0570-0833
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