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Synthese und Trennung der Enantiomere des konfigurationsstabilen Tris(tetrachlorbenzoldiolato)phosphat(V)-Ions

Ginglinger, Catherine
Published in Angewandte Chemie. 1997, vol. 109, no. 6, p. 660-662
Abstract Easily accessible and configurationally stable are words that describe the enantiopure tris(tetrachlorobenzenediolato)phosphate(V) ion (1). These qualities predetermine 1 for use in enantiomeric resolution and asymmetric synthesis. X-ray structure analysis of the cinchonidinium salt of 1 confirmed the octahedral geometry and provided the absolute configuration of the anion.
Keywords ChiralityCinchonidineEnantiomeric resolutionPhosphorus
Note Paru également dans Angewandte Chemie: International Edition in English sous le titre:"Synthesis and Resolution of the Configurationally Stable Tris(tetrachlorobenzenediolato)phosphate Anion" en 1997, 37(6), 608-610
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LACOUR, Jérôme et al. Synthese und Trennung der Enantiomere des konfigurationsstabilen Tris(tetrachlorbenzoldiolato)phosphat(V)-Ions. In: Angewandte Chemie, 1997, vol. 109, n° 6, p. 660-662. doi: 10.1002/ange.19971090628 https://archive-ouverte.unige.ch/unige:6973

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Deposited on : 2010-06-18

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