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Desymmetrization of a meso-diol complex derived from [Cr(CO)3(η6-5,8-naphthoquinone)]: use of new diamine acylation catalysts

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Published in Chemical Communications. 2004, vol. 39, no. 13, p. 1548-1549
Abstract [Cr(CO)3(naphthoquinone)](1), prepared in a three-step sequence starting from 1,4-dihydroxynaphthalene, was reduced to the corresponding meso-dihydronaphthalene syn-diol complex and the latter was desymmetrized to give the mono-acyl complex with 99% ee via asymmetric acylation catalyzed by the two new and easily accessed chiral diamines 7 and 8.
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PMID: 15216374
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KUNDIG, Ernst Peter et al. Desymmetrization of a meso-diol complex derived from [Cr(CO)3(η6-5,8-naphthoquinone)]: use of new diamine acylation catalysts. In: Chemical Communications, 2004, vol. 39, n° 13, p. 1548-1549. https://archive-ouverte.unige.ch/unige:6967

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Deposited on : 2010-06-18

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