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Novel Heteroleptic cis-(C^N2)Pd(II) Chelates for the Preparation of Enantiopure Planar Chiral Cyclopalladated 2-[tricarbonyl(η6-phenyl)chromium]pyridine

Authors
Berger, Alexsandro
Djukic, Jean-Pierre
Pfeffer, Michel
de Cian, André
Kyritsakas-Gruber, Nathalie
Published in Chemical Communications. 2003, vol. 38, no. 5, p. 658
Abstract In the presence of large amounts of [Me4N]Cl, the reaction of ortho-chloromercurated 2-[(n6-phenyl)tricarbonylchromium]pyridine with µ-chloro cyclopalladated aromatic compounds yields a series of new heteroleptic heterodinuclear cis-(C^N)2Pd(II) complexes, which are valuable precursors of planar chiral cyclopalladated (n6-arene)Cr(CO)3 complexes.
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BERGER, Alexsandro et al. Novel Heteroleptic cis-(C^N2)Pd(II) Chelates for the Preparation of Enantiopure Planar Chiral Cyclopalladated 2-[tricarbonyl(η6-phenyl)chromium]pyridine. In: Chemical Communications, 2003, vol. 38, n° 5, p. 658. https://archive-ouverte.unige.ch/unige:6966

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Deposited on : 2010-06-18

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