Conformational Preference and Configurational Control of Highly Symmetric Spirobi[dibenzazepinium] Cation

Vial, Laurent; Lacour, Jérôme

doi:10.1021/ol026800r

Scientific article

Letter

English

Conformational Preference and Configurational Control of Highly Symmetric Spirobi[dibenzazepinium] Cation

ContributorsVial, Laurent; Lacour, Jérôme

Published inOrganic letters, vol. 4, no. 22, p. 3939-3942

Publication date2002

Abstract

Stereodynamics were detected in solution for salts of the simple spirobi[dibenzazepinium] cation in favor of the homochiral (D2) conformer as evidenced by chiral TRISPHAT and BINPHAT counterions; asymmetric induction was furthermore observed in 1H and 15N NMR spectroscopy.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

VIAL, Laurent, LACOUR, Jérôme. Conformational Preference and Configurational Control of Highly Symmetric Spirobi[dibenzazepinium] Cation. In: Organic letters, 2002, vol. 4, n° 22, p. 3939–3942. doi: 10.1021/ol026800r

Article

Identifiers

PID : unige:6959
DOI : 10.1021/ol026800r

Journal ISSN1523-7052

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Conformational Preference and Configurational Control of Highly Symmetric Spirobi[dibenzazepinium] Cation

Stereodynamics were detected in solution for salts of the simple spirobi[dibenzazepinium] cation in favor of the homochiral (D2) conformer as evidenced by chiral TRISPHAT and BINPHAT counterions; asymmetric induction was furthermore observed in 1H and 15N NMR spectroscopy.

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