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Conformational Preference and Configurational Control of Highly Symmetric Spirobi[dibenzazepinium] Cation

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Published in Organic Letters. 2002, vol. 4, no. 22, p. 3939-3942
Abstract Stereodynamics were detected in solution for salts of the simple spirobi[dibenzazepinium] cation in favor of the homochiral (D2) conformer as evidenced by chiral TRISPHAT and BINPHAT counterions; asymmetric induction was furthermore observed in 1H and 15N NMR spectroscopy.
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VIAL, Laurent, LACOUR, Jérôme. Conformational Preference and Configurational Control of Highly Symmetric Spirobi[dibenzazepinium] Cation. In: Organic Letters, 2002, vol. 4, n° 22, p. 3939-3942. https://archive-ouverte.unige.ch/unige:6959

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Deposited on : 2010-06-18

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