One-Step Stereoselective Synthesis and NMR Chiral Shift Properties of a Novel Hexacoordinated Phosphorus Cation

Lacour, Jérôme; Vial, Laurent; Bernardinelli, Gérald Hugues

doi:10.1021/ol026152b

Scientific article

Letter

English

One-Step Stereoselective Synthesis and NMR Chiral Shift Properties of a Novel Hexacoordinated Phosphorus Cation

Contributors

Lacour, Jérôme

; Vial, Laurent; Bernardinelli, Gérald Hugues

Published in

Organic letters, vol. 4, no. 14, p. 2309-2312

Publication date

2002

Abstract

Tropolone, binol, and PCl(5) react in CH(2)Cl(2) at reflux to generate in one step a novel C(2)-symmetric hexacoordinated phosphorus cation of configuration controlled by the binol ligand. It behaves as an efficient NMR chiral shift agent for chiral anionic phosphate and borate anions.

UNIGE affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

LACOUR, Jérôme, VIAL, Laurent, BERNARDINELLI, Gérald Hugues. One-Step Stereoselective Synthesis and NMR Chiral Shift Properties of a Novel Hexacoordinated Phosphorus Cation. In: Organic letters, 2002, vol. 4, n° 14, p. 2309–2312. doi: 10.1021/ol026152b

Article

Identifiers

PID : unige:6958
DOI : 10.1021/ol026152b
PMID : 12098234

Journal ISSN

1523-7052

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Creation

18/06/2010 08:54:42

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18/06/2010 08:54:42

Update

14/03/2023 15:30:27

Status update

14/03/2023 15:30:27

Last indexation

10/06/2025 21:33:32

One-Step Stereoselective Synthesis and NMR Chiral Shift Properties of a Novel Hexacoordinated Phosphorus Cation

Contributors

Published in

Publication date

Abstract

UNIGE affiliation entities

Citation (ISO format)

Main files (1)

Identifiers

Journal ISSN

Technical informations

Creation

First validation

Update

Status update

Last indexation