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One-Step Stereoselective Synthesis and NMR Chiral Shift Properties of a Novel Hexacoordinated Phosphorus Cation |
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Published in | Organic letters. 2002, vol. 4, no. 14, p. 2309-2312 | |
Abstract | Tropolone, binol, and PCl(5) react in CH(2)Cl(2) at reflux to generate in one step a novel C(2)-symmetric hexacoordinated phosphorus cation of configuration controlled by the binol ligand. It behaves as an efficient NMR chiral shift agent for chiral anionic phosphate and borate anions. | |
Identifiers | DOI: 10.1021/ol026152b PMID: 12098234 | |
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Citation (ISO format) | LACOUR, Jérôme, VIAL, Laurent, BERNARDINELLI, Gérald Hugues. One-Step Stereoselective Synthesis and NMR Chiral Shift Properties of a Novel Hexacoordinated Phosphorus Cation. In: Organic letters, 2002, vol. 4, n° 14, p. 2309-2312. doi: 10.1021/ol026152b https://archive-ouverte.unige.ch/unige:6958 |