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Scientific article
Letter
English

One-Step Stereoselective Synthesis and NMR Chiral Shift Properties of a Novel Hexacoordinated Phosphorus Cation

Published inOrganic letters, vol. 4, no. 14, p. 2309-2312
Publication date2002
Abstract

Tropolone, binol, and PCl(5) react in CH(2)Cl(2) at reflux to generate in one step a novel C(2)-symmetric hexacoordinated phosphorus cation of configuration controlled by the binol ligand. It behaves as an efficient NMR chiral shift agent for chiral anionic phosphate and borate anions.

Citation (ISO format)
LACOUR, Jérôme, VIAL, Laurent, BERNARDINELLI, Gérald Hugues. One-Step Stereoselective Synthesis and NMR Chiral Shift Properties of a Novel Hexacoordinated Phosphorus Cation. In: Organic letters, 2002, vol. 4, n° 14, p. 2309–2312. doi: 10.1021/ol026152b
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ISSN of the journal1523-7052
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