One-Step Stereoselective Synthesis and NMR Chiral Shift Properties of a Novel Hexacoordinated Phosphorus Cation

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Title		One-Step Stereoselective Synthesis and NMR Chiral Shift Properties of a Novel Hexacoordinated Phosphorus Cation
Authors		Lacour, Jérôme Vial, Laurent Bernardinelli, Gérald Hugues
Published in		Organic Letters. 2002, vol. 4, no. 14, p. 2309-2312
Abstract		Tropolone, binol, and PCl(5) react in CH(2)Cl(2) at reflux to generate in one step a novel C(2)-symmetric hexacoordinated phosphorus cation of configuration controlled by the binol ligand. It behaves as an efficient NMR chiral shift agent for chiral anionic phosphate and borate anions.
Identifiers		DOI: 10.1021/ol026152b PMID: 12098234
Full text		Article - Limited access to UNIGE
Structures		Faculté des sciences / Section de chimie et biochimie / Département de chimie organique
Citation (ISO format)		LACOUR, Jérôme, VIAL, Laurent, BERNARDINELLI, Gérald Hugues. One-Step Stereoselective Synthesis and NMR Chiral Shift Properties of a Novel Hexacoordinated Phosphorus Cation. In: Organic Letters, 2002, vol. 4, n° 14, p. 2309-2312. https://archive-ouverte.unige.ch/unige:6958