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Rapid Access to Synthetic Lysobisphosphatidic Acids Using PIII Chemistry

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Published in Organic Letters. 2000, vol. 2, no. 13, p. 1859-1861
Abstract An expeditious route to synthetic lysobisphosphatidic acid S,S-1, its enantiomer, and regioisomers is reported. Synthetic difficulties concerning lipid stability and stereochemistry are bypassed using a phosphite triester approach in combination with multiple silyl protection. Spectroscopic studies evidence that acyl group migration in S,S-1 is accelerated by nonpolar solvents and inhibited by pyridine.
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PMID: 10891176
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CHEVALLIER, Julien et al. Rapid Access to Synthetic Lysobisphosphatidic Acids Using PIII Chemistry. In: Organic Letters, 2000, vol. 2, n° 13, p. 1859-1861. https://archive-ouverte.unige.ch/unige:6954

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Deposited on : 2010-06-18

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