UNIGE document Scientific Article - Letter
previous document  unige:6952  next document
add to browser collection
Title

Synthesis of (-)-Lasubine(I) via a Planar Chiral [(η6-Arene)Cr(CO)3] Complex

Authors
Published in Organic Letters. 1999, vol. 1, no. 12, p. 1997-1999
Abstract Key steps of the synthesis of the Lythraceae alkaloid (-)-lasubine(I) are the formation of an enantiopure planar chiral arylaldehyde tricarbonylchromium complex and highly diastereoselective aza-Diels-Alder cycloaddition and intramolecular radical cyclization reactions to afford a quinolizidinone intermediate. Ketone reduction, desilylation, and decomplexation yield the enantiomerically pure product.
Identifiers
Full text
Article - document accessible for UNIGE members only Limited access to UNIGE
Structures
Citation
(ISO format)
RATNI, Hasane, KUNDIG, Ernst Peter. Synthesis of (-)-Lasubine(I) via a Planar Chiral [(η6-Arene)Cr(CO)3] Complex. In: Organic Letters, 1999, vol. 1, n° 12, p. 1997-1999. https://archive-ouverte.unige.ch/unige:6952

221 hits

40 downloads

Update

Deposited on : 2010-06-18

Export document
Format :
Citation style :