Large-Scale Synthesis and Resolution of TRISPHAT [Tris(tetrachlorobenzenediolato) phosphate(V)] Anion

Favarger, France; Goujon-Ginglinger, Catherine; Monchaud, David; Lacour, Jérôme

doi:10.1021/jo048641q

Scientific article

English

Large-Scale Synthesis and Resolution of TRISPHAT [Tris(tetrachlorobenzenediolato) phosphate(V)] Anion

ContributorsFavarger, France; Goujon-Ginglinger, Catherine; Monchaud, David; Lacour, Jérôme

Published inJournal of organic chemistry, vol. 69, no. 24, p. 8521-8524

Publication date2004

Abstract

Both enantiomers of TRISPHAT anion can be obtained on a multigram scale through a novel resolution procedure. The Lambda enantiomer is isolated as the tri-n-butylammonium salt, [(n)()Bu(3)NH][Lambda-1], which is soluble in pure CHCl(3) and CH(2)Cl(2). The Delta enantiomer is prepared as the cinchonidinium derivative, which is only soluble in polar solvent mixtures (>7.5% DMSO in CHCl(3)).

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

FAVARGER, France et al. Large-Scale Synthesis and Resolution of TRISPHAT [Tris(tetrachlorobenzenediolato) phosphate(V)] Anion. In: Journal of organic chemistry, 2004, vol. 69, n° 24, p. 8521–8524. doi: 10.1021/jo048641q

Article

Identifiers

PID : unige:6949
DOI : 10.1021/jo048641q
PMID : 15549835

Journal ISSN0022-3263

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Large-Scale Synthesis and Resolution of TRISPHAT [Tris(tetrachlorobenzenediolato) phosphate(V)] Anion

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