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Title

Bent Structure and Dynamic Stereochemistry of Chiral Acridinium Cations

Authors
Laursen, Bo W.
Published in Journal of Organic Chemistry. 2003, vol. 68, no. 16, p. 6304-6308
Abstract Chiral acridinium cations, easily prepared by reaction of enantiopure primary amines and tris(2,6-dimethoxy)trityl cation, display restricted rotations around the C(sp(3))-N(sp(2)) bond. A bending of the aromatic backbone and "out-of-plane" displacements of C(9) and N(10) atoms are enforced if bulky amines are introduced.
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PMID: 12895064
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LALEU, Benoît et al. Bent Structure and Dynamic Stereochemistry of Chiral Acridinium Cations. In: Journal of Organic Chemistry, 2003, vol. 68, n° 16, p. 6304-6308. https://archive-ouverte.unige.ch/unige:6948

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Deposited on : 2010-06-18

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