Bent Structure and Dynamic Stereochemistry of Chiral Acridinium Cations

Laleu, Benoît; Herse, Christelle; Laursen, Bo W.; Bernardinelli, Gérald Hugues; Lacour, Jérôme

doi:10.1021/jo0345998

Scientific article

English

Bent Structure and Dynamic Stereochemistry of Chiral Acridinium Cations

ContributorsLaleu, Benoît; Herse, Christelle; Laursen, Bo W.; Bernardinelli, Gérald Hugues; Lacour, Jérôme

Published inJournal of organic chemistry, vol. 68, no. 16, p. 6304-6308

Publication date2003

Abstract

Chiral acridinium cations, easily prepared by reaction of enantiopure primary amines and tris(2,6-dimethoxy)trityl cation, display restricted rotations around the C(sp(3))-N(sp(2)) bond. A bending of the aromatic backbone and "out-of-plane" displacements of C(9) and N(10) atoms are enforced if bulky amines are introduced.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

LALEU, Benoît et al. Bent Structure and Dynamic Stereochemistry of Chiral Acridinium Cations. In: Journal of organic chemistry, 2003, vol. 68, n° 16, p. 6304–6308. doi: 10.1021/jo0345998

Article

Identifiers

PID : unige:6948
DOI : 10.1021/jo0345998
PMID : 12895064

Journal ISSN0022-3263

622views

0downloads

Creation18/06/2010 08:54:37

First validation18/06/2010 08:54:37

Update time14/03/2023 15:30:24

Status update14/03/2023 15:30:24

Last indexation29/10/2024 15:02:55

Archive ouverte UNIGE

Bent Structure and Dynamic Stereochemistry of Chiral Acridinium Cations

Technical informations