TRISPHAT-N: A Chiral Hexacoordinated Phosphate Anion with Unique Asymmetric Coordinating Properties

Constant, Samuel Claude; Frantz, Richard; Müller, Jessica; Bernardinelli, Gérald Hugues; Lacour, Jérôme

doi:10.1021/om070074k

Scientific article

English

TRISPHAT-N: A Chiral Hexacoordinated Phosphate Anion with Unique Asymmetric Coordinating Properties

Contributors

Constant, Samuel Claude; Frantz, Richard; Müller, Jessica; Bernardinelli, Gérald Hugues; Lacour, Jérôme

Published in

Organometallics, vol. 26, no. 9, p. 2141-2143

Publication date

2007

Abstract

A simple and efficient chiral anionic N-ligand: the introduction of a Lewis basic nitrogen onto the TRISPHAT skeleton allows the direct and efficient stereocontrol of tropos chiral ligands bound to metal complexes or of stereogenic metal centers (dr up to 96:4).

UNIGE affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

CONSTANT, Samuel Claude et al. TRISPHAT-N: A Chiral Hexacoordinated Phosphate Anion with Unique Asymmetric Coordinating Properties. In: Organometallics, 2007, vol. 26, n° 9, p. 2141–2143. doi: 10.1021/om070074k

Article

Identifiers

PID : unige:6934
DOI : 10.1021/om070074k

Journal ISSN

0276-7333

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Creation

18/06/2010 08:54:28

First validation

18/06/2010 08:54:28

Update

14/03/2023 15:30:20

Status update

14/03/2023 15:30:20

Last indexation

10/06/2025 21:33:07

TRISPHAT-N: A Chiral Hexacoordinated Phosphate Anion with Unique Asymmetric Coordinating Properties

Contributors

Published in

Publication date

Abstract

UNIGE affiliation entities

Citation (ISO format)

Main files (1)

Identifiers

Journal ISSN

Technical informations

Creation

First validation

Update

Status update

Last indexation