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Scientific article
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Kinetic Resolution of Diols and Pyridyl Alcohols by Cu(II)(borabox)-Catalyzed Acylation

Published inOrganic letters, vol. 8, no. 9, p. 1879-1882
Publication date2006
Abstract

Boron-bridged bisoxazoline (borabox) ligands have been used in the copper(II)-catalyzed benzoylation of pyridyl alcohols and 1,2-diols. Efficient kinetic resolution of 1,2-diols was achieved using both borabox and bisoxazoline (box) ligands. Borabox ligands induced high selectivities in the benzoylation of suitable pyridyl alcohols, where they outperformed bisoxazolines. In addition, highly enantioselective Cu(II)(borabox)-catalyzed benzoylation has been used for the synthesis of both enantiomers of a pyridyl alcohol.

Affiliation Not a UNIGE publication
Citation (ISO format)
MAZET, Clement et al. Kinetic Resolution of Diols and Pyridyl Alcohols by Cu(II)(borabox)-Catalyzed Acylation. In: Organic letters, 2006, vol. 8, n° 9, p. 1879–1882. doi: 10.1021/ol060443t
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ISSN of the journal1523-7052
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