Triazatriangulenium Cations: Highly Stable Carbocations for Phase-Transfer Catalysis

Nicolas, Cyril Michel; Lacour, Jérôme

doi:10.1021/ol0617392

Scientific article

English

Triazatriangulenium Cations: Highly Stable Carbocations for Phase-Transfer Catalysis

ContributorsNicolas, Cyril Michel; Lacour, Jérôme

Published inOrganic letters, vol. 8, no. 19, p. 4343-4346

Publication date2006

Abstract

Highly stable triazatriangulenium carbocations, of pK(R+) higher than 20, can be used as novel phase-transfer catalysts for several classical organic reactions, their intrinsic stability in strongly basic and nucleophilic conditions rendering this novel use feasible.

Affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

NICOLAS, Cyril Michel, LACOUR, Jérôme. Triazatriangulenium Cations: Highly Stable Carbocations for Phase-Transfer Catalysis. In: Organic letters, 2006, vol. 8, n° 19, p. 4343–4346. doi: 10.1021/ol0617392

Article

Identifiers

PID : unige:6932
DOI : 10.1021/ol0617392
PMID : 16956222

ISSN of the journal1523-7052

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Triazatriangulenium Cations: Highly Stable Carbocations for Phase-Transfer Catalysis

Highly stable triazatriangulenium carbocations, of pK(R+) higher than 20, can be used as novel phase-transfer catalysts for several classical organic reactions, their intrinsic stability in strongly basic and nucleophilic conditions rendering this novel use feasible.

Technical informations