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On the enantioselective olefin epoxidation by doubly bridged biphenyl azepines derivatives – mixed tropos/atropos chiral biaryls

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Published in Organic and Biomolecular Chemistry. 2007, vol. 5, no. 3, p. 501-506
Abstract Diastereomeric doubly bridged biphenyl azepines, atropos at 20 degrees C and tropos at 80 degrees C, are precursors to effective iminium organocatalysts that are employed in the enantioselective epoxidation of prochiral olefins (up to 85% ee).
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PMID: 17252133
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VACHON, Jérôme et al. On the enantioselective olefin epoxidation by doubly bridged biphenyl azepines derivatives – mixed tropos/atropos chiral biaryls. In: Organic and Biomolecular Chemistry, 2007, vol. 5, n° 3, p. 501-506. https://archive-ouverte.unige.ch/unige:6929

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Deposited on : 2010-06-18

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