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Scientific article
English

On the enantioselective olefin epoxidation by doubly bridged biphenyl azepines derivatives – mixed tropos/atropos chiral biaryls

Published inOrganic & biomolecular chemistry, vol. 5, no. 3, p. 501-506
Publication date2007
Abstract

Diastereomeric doubly bridged biphenyl azepines, atropos at 20 degrees C and tropos at 80 degrees C, are precursors to effective iminium organocatalysts that are employed in the enantioselective epoxidation of prochiral olefins (up to 85% ee).

Citation (ISO format)
VACHON, Jérôme et al. On the enantioselective olefin epoxidation by doubly bridged biphenyl azepines derivatives – mixed tropos/atropos chiral biaryls. In: Organic & biomolecular chemistry, 2007, vol. 5, n° 3, p. 501–506. doi: 10.1039/b615797a
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ISSN of the journal1477-0520
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