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Trimesitylmethylphosphonium Cation. Supramolecular Stereocontrol and Simple Enantiomerization Mechanism Determination

Authors
Chauvin, Remi
Published in Journal of organic chemistry. 2006, vol. 71, no. 19, p. 7412-7416
Abstract Stereocontrol over the propeller isomerism of trimesitylmethylphosphonium cation was achieved through an ion pairing with chiral hexacoordinated phosphate anions; the asymmetric ion pairing allowed also a most simple experimental proof of the nature of the enantiomerization pathway in solution (two-ring flip).
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PMID: 16958536
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LALEU, Benoît et al. Trimesitylmethylphosphonium Cation. Supramolecular Stereocontrol and Simple Enantiomerization Mechanism Determination. In: Journal of organic chemistry, 2006, vol. 71, n° 19, p. 7412-7416. doi: 10.1021/jo061097w https://archive-ouverte.unige.ch/unige:6916

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Deposited on : 2010-06-18

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