en
Scientific article
English

Trimesitylmethylphosphonium Cation. Supramolecular Stereocontrol and Simple Enantiomerization Mechanism Determination

Published inJournal of organic chemistry, vol. 71, no. 19, p. 7412-7416
Publication date2006
Abstract

Stereocontrol over the propeller isomerism of trimesitylmethylphosphonium cation was achieved through an ion pairing with chiral hexacoordinated phosphate anions; the asymmetric ion pairing allowed also a most simple experimental proof of the nature of the enantiomerization pathway in solution (two-ring flip).

Citation (ISO format)
LALEU, Benoît et al. Trimesitylmethylphosphonium Cation. Supramolecular Stereocontrol and Simple Enantiomerization Mechanism Determination. In: Journal of organic chemistry, 2006, vol. 71, n° 19, p. 7412–7416. doi: 10.1021/jo061097w
Main files (1)
Article
accessLevelRestricted
Identifiers
ISSN of the journal0022-3263
462views
0downloads

Technical informations

Creation06/18/2010 8:54:18 AM
First validation06/18/2010 8:54:18 AM
Update time03/14/2023 3:30:15 PM
Status update03/14/2023 3:30:15 PM
Last indexation02/12/2024 6:23:05 PM
All rights reserved by Archive ouverte UNIGE and the University of GenevaunigeBlack