Trimesitylmethylphosphonium Cation. Supramolecular Stereocontrol and Simple Enantiomerization Mechanism Determination

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Title		Trimesitylmethylphosphonium Cation. Supramolecular Stereocontrol and Simple Enantiomerization Mechanism Determination
Authors		Laleu, Benoît Bernardinelli, Gérald Hugues Chauvin, Remi Lacour, Jérôme
Published in		Journal of organic chemistry. 2006, vol. 71, no. 19, p. 7412-7416
Abstract		Stereocontrol over the propeller isomerism of trimesitylmethylphosphonium cation was achieved through an ion pairing with chiral hexacoordinated phosphate anions; the asymmetric ion pairing allowed also a most simple experimental proof of the nature of the enantiomerization pathway in solution (two-ring flip).
Identifiers		DOI: 10.1021/jo061097w PMID: 16958536
Full text		Article - Limited access to UNIGE
Structures		Faculté des sciences / Section de chimie et biochimie / Département de chimie organique
Citation (ISO format)		LALEU, Benoît et al. Trimesitylmethylphosphonium Cation. Supramolecular Stereocontrol and Simple Enantiomerization Mechanism Determination. In: Journal of organic chemistry, 2006, vol. 71, n° 19, p. 7412-7416. doi: 10.1021/jo061097w https://archive-ouverte.unige.ch/unige:6916