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Scientific article
English

Stereoselective dimerization of racemic C3-symmetric Ti(IV) amine triphenolate complexes

Published inDalton transactions, no. 16, p. 1573-1576
Publication date2007
Abstract

A novel, mononuclear Ti(IV) amine triphenolate complex obtained by reaction of Ti(OiPr)(4) with tris(2-hydroxy-3-phenylbenzyl)amine bearing phenyl ortho-substituents affords quantitatively and spontaneously the corresponding heterochiral micro-oxo dinuclear compound whereas an analogous chiral, enantiopure complex maintains its mononuclear structure even in the presence of an excess of water.

Citation (ISO format)
BERNARDINELLI, Gérald Hugues et al. Stereoselective dimerization of racemic C3-symmetric Ti(IV) amine triphenolate complexes. In: Dalton transactions, 2007, n° 16, p. 1573–1576. doi: 10.1039/b702958f
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ISSN of the journal1477-9226
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