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Title

Stereoselective dimerization of racemic C3-symmetric Ti(IV) amine triphenolate complexes

Authors
Prins, Leonard J.
Kolarvoic, Andrej
Mba, Miriam
Pontini, Marta
Licini, Giulia
Published in Dalton Transactions. 2007, no. 16, p. 1573-1576
Abstract A novel, mononuclear Ti(IV) amine triphenolate complex obtained by reaction of Ti(OiPr)(4) with tris(2-hydroxy-3-phenylbenzyl)amine bearing phenyl ortho-substituents affords quantitatively and spontaneously the corresponding heterochiral micro-oxo dinuclear compound whereas an analogous chiral, enantiopure complex maintains its mononuclear structure even in the presence of an excess of water.
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PMID: 17426858
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BERNARDINELLI, Gérald Hugues et al. Stereoselective dimerization of racemic C3-symmetric Ti(IV) amine triphenolate complexes. In: Dalton Transactions, 2007, n° 16, p. 1573-1576. doi: 10.1039/b702958f https://archive-ouverte.unige.ch/unige:6911

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Deposited on : 2010-06-18

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