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Pummerer fragmentation vs. Pummerer rearrangement: a mechanistic analysis

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Machado, Marco Santarem
Published in Chemical Communications. 2006, no. 26, p. 2786-2788
Abstract Depending upon the nature of the substituent at the β-position of the sulfoxide moiety, a Pummerer reaction can be oriented "at will" towards Cα–H (rearrangement) or Cα–Cβ (fragmentation) bond cleavage.
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LALEU, Benoît, MACHADO, Marco Santarem, LACOUR, Jérôme. Pummerer fragmentation vs. Pummerer rearrangement: a mechanistic analysis. In: Chemical Communications, 2006, n° 26, p. 2786-2788. https://archive-ouverte.unige.ch/unige:6907

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Deposited on : 2010-06-18

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