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Pummerer fragmentation vs. Pummerer rearrangement: a mechanistic analysis |
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Published in | Chemical communications. 2006, no. 26, p. 2786-2788 | |
Abstract | Depending upon the nature of the substituent at the β-position of the sulfoxide moiety, a Pummerer reaction can be oriented "at will" towards Cα–H (rearrangement) or Cα–Cβ (fragmentation) bond cleavage. | |
Identifiers | DOI: 10.1039/b605187a | |
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Citation (ISO format) | LALEU, Benoît, MACHADO, Marco Santarem, LACOUR, Jérôme. Pummerer fragmentation vs. Pummerer rearrangement: a mechanistic analysis. In: Chemical communications, 2006, n° 26, p. 2786-2788. doi: 10.1039/b605187a https://archive-ouverte.unige.ch/unige:6907 |