Scientific article
English

Pummerer fragmentation vs. Pummerer rearrangement: a mechanistic analysis

Published inChemical communications, no. 26, p. 2786-2788
Publication date2006
Abstract

Depending upon the nature of the substituent at the β-position of the sulfoxide moiety, a Pummerer reaction can be oriented "at will" towards Cα–H (rearrangement) or Cα–Cβ (fragmentation) bond cleavage.

Citation (ISO format)
LALEU, Benoît, MACHADO, Marco Santarem, LACOUR, Jérôme. Pummerer fragmentation vs. Pummerer rearrangement: a mechanistic analysis. In: Chemical communications, 2006, n° 26, p. 2786–2788. doi: 10.1039/b605187a
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Identifiers
Journal ISSN1359-7345
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