Enantiodifferentiation of chiral cationic cages using trapped achiral BF4- anions as chirotopic probes

Frantz, Richard; Grange, Christopher S.; Al-Rasbi, Nawal K.; Ward, Michael D.; Lacour, Jérôme

doi:10.1039/b618092b

Scientific article

English

Enantiodifferentiation of chiral cationic cages using trapped achiral BF4- anions as chirotopic probes

ContributorsFrantz, Richard; Grange, Christopher S.; Al-Rasbi, Nawal K.; Ward, Michael D.; Lacour, Jérôme

Published inChemical communications, no. 14, p. 1459-1461

Publication date2007

Abstract

The addition of enantiopure TRISPHAT anions to chiral cationic cages of type [Co(4)(L)(6)(BF(4))](7+) leads to the enantiodifferentiation of the ligands of the racemic salts and, even more effectively, of the achiral tetrafluoroborate anion trapped inside.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

FRANTZ, Richard et al. Enantiodifferentiation of chiral cationic cages using trapped achiral BF4- anions as chirotopic probes. In: Chemical communications, 2007, n° 14, p. 1459–1461. doi: 10.1039/b618092b

Article

Identifiers

PID : unige:6905
DOI : 10.1039/b618092b
PMID : 17389992

Journal ISSN1359-7345

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Enantiodifferentiation of chiral cationic cages using trapped achiral BF4- anions as chirotopic probes

The addition of enantiopure TRISPHAT anions to chiral cationic cages of type [Co(4)(L)(6)(BF(4))](7+) leads to the enantiodifferentiation of the ligands of the racemic salts and, even more effectively, of the achiral tetrafluoroborate anion trapped inside.

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