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Title

Enantiodifferentiation of chiral cationic cages using trapped achiral BF4- anions as chirotopic probes

Authors
Grange, Christopher S.
Al-Rasbi, Nawal K.
Ward, Michael D.
Published in Chemical Communications. 2007, no. 14, p. 1459-1461
Abstract The addition of enantiopure TRISPHAT anions to chiral cationic cages of type [Co(4)(L)(6)(BF(4))](7+) leads to the enantiodifferentiation of the ligands of the racemic salts and, even more effectively, of the achiral tetrafluoroborate anion trapped inside.
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PMID: 17389992
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FRANTZ, Richard et al. Enantiodifferentiation of chiral cationic cages using trapped achiral BF4- anions as chirotopic probes. In: Chemical Communications, 2007, n° 14, p. 1459-1461. doi: 10.1039/b618092b https://archive-ouverte.unige.ch/unige:6905

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Deposited on : 2010-06-18

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