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Title

Air- and Microwave Stable (C5H5)Ru Catalysts for Improved Regio- and Enantioselective Carroll Rearrangements

Authors
Müller, Jessica
Published in Angewandte Chemie: International Edition. 2007, vol. 46, no. 47, p. 8979-8982
Abstract Reduce, reuse, recycle: Zwitterionic adducts of pyridyl-containing hexacoordinate phosphorus anions and (C5H5)Ru moieties (see picture) are air-, moisture-, and microwave-stable catalysts that can be readily purified and in some instances recycled. Carroll rearrangements of allylic -ketoesters performed with these species occur with improved regio- and enantioselectivity.
Keywords Allyl complexesEnantioselectivityHomogeneous catalysisN ligandsRuthenium
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PMID: 17972257
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CONSTANT, Samuel Claude et al. Air- and Microwave Stable (C5H5)Ru Catalysts for Improved Regio- and Enantioselective Carroll Rearrangements. In: Angewandte Chemie: International Edition, 2007, vol. 46, n° 47, p. 8979-8982. https://archive-ouverte.unige.ch/unige:6901

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Deposited on : 2010-06-18

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