An Enantioselective CpRu Catalyzed Carroll Rearrangement

Constant, Samuel Claude; Tortoioli, Simone; Müller, Jessica; Lacour, Jérôme

doi:10.1002/anie.200604573

Scientific article

English

An Enantioselective CpRu Catalyzed Carroll Rearrangement

ContributorsConstant, Samuel Claude; Tortoioli, Simone; Müller, Jessica; Lacour, Jérôme

Published inAngewandte Chemie, vol. 46, no. 12, p. 2082-2085

Publication date2007

Abstract

Simple ligands, catalyst, and conditions: The combination of readily prepared unsymmetrical pyridine-imine ligands and [CpRu(CH3CN)3][PF6] (Cp=C5H5) affords regio- and enantioselective Carroll rearrangements (see scheme; b/l= branched-to-linear ratio). This reaction represents the first example of Ru-catalyzed enantioselective CC bond-forming allylic substitution.

Keywords

C--C coupling
Enantioselectivity
N ligands
Rearrangement
Ruthenium

NoteThis study was highlighted in Synfacts.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

CONSTANT, Samuel Claude et al. An Enantioselective CpRu Catalyzed Carroll Rearrangement. In: Angewandte Chemie, 2007, vol. 46, n° 12, p. 2082–2085. doi: 10.1002/anie.200604573

Article

Identifiers

PID : unige:6899
DOI : 10.1002/anie.200604573
PMID : 17278172

Journal ISSN1433-7851

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An Enantioselective CpRu Catalyzed Carroll Rearrangement

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