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Title

An Enantioselective CpRu Catalyzed Carroll Rearrangement

Authors
Müller, Jessica
Published in Angewandte Chemie: International Edition. 2007, vol. 46, no. 12, p. 2082-2085
Abstract Simple ligands, catalyst, and conditions: The combination of readily prepared unsymmetrical pyridine-imine ligands and [CpRu(CH3CN)3][PF6] (Cp=C5H5) affords regio- and enantioselective Carroll rearrangements (see scheme; b/l= branched-to-linear ratio). This reaction represents the first example of Ru-catalyzed enantioselective CC bond-forming allylic substitution.
Keywords C--C couplingEnantioselectivityN ligandsRearrangementRuthenium
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PMID: 17278172
Note This study was highlighted in Synfacts.
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CONSTANT, Samuel Claude et al. An Enantioselective CpRu Catalyzed Carroll Rearrangement. In: Angewandte Chemie: International Edition, 2007, vol. 46, n° 12, p. 2082-2085. https://archive-ouverte.unige.ch/unige:6899

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Deposited on : 2010-06-18

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