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Scientific article
English

An Enantioselective CpRu Catalyzed Carroll Rearrangement

Published inAngewandte Chemie, vol. 46, no. 12, p. 2082-2085
Publication date2007
Abstract

Simple ligands, catalyst, and conditions: The combination of readily prepared unsymmetrical pyridine-imine ligands and [CpRu(CH3CN)3][PF6] (Cp=C5H5) affords regio- and enantioselective Carroll rearrangements (see scheme; b/l= branched-to-linear ratio). This reaction represents the first example of Ru-catalyzed enantioselective CC bond-forming allylic substitution.

Keywords
  • C--C coupling
  • Enantioselectivity
  • N ligands
  • Rearrangement
  • Ruthenium
NoteThis study was highlighted in Synfacts.
Citation (ISO format)
CONSTANT, Samuel Claude et al. An Enantioselective CpRu Catalyzed Carroll Rearrangement. In: Angewandte Chemie, 2007, vol. 46, n° 12, p. 2082–2085. doi: 10.1002/anie.200604573
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ISSN of the journal1433-7851
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