Catalytic Enantioselective Hydrogenolysis of [Cr(CO)3(5,8-Dibromonaphthalene)]

Kundig, Ernst Peter; Chaudhuri, Piyali Datta; House, David; Bernardinelli, Gérald Hugues

doi:10.1002/anie.200502688

Scientific article

English

Catalytic Enantioselective Hydrogenolysis of [Cr(CO)3(5,8-Dibromonaphthalene)]

ContributorsKundig, Ernst Peter; Chaudhuri, Piyali Datta; House, David; Bernardinelli, Gérald Hugues

Published inAngewandte Chemie, vol. 45, no. 7, p. 1092-1095

Publication date2006

Abstract

Split and run: A study of the asymmetric hydrogenolysis of an aryl-carbon-bromine bond in a naphthalene chromiumtricarbonyl complex shows the use of a new bulky phosphoramidite ligand to yield the product in highly enantiomerically enriched form (see scheme).

Keywords

Asymmetric synthesis
Chromium
Hydrogenolysis
P ligands
Palladium

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

KUNDIG, Ernst Peter et al. Catalytic Enantioselective Hydrogenolysis of [Cr(CO)3(5,8-Dibromonaphthalene)]. In: Angewandte Chemie, 2006, vol. 45, n° 7, p. 1092–1095. doi: 10.1002/anie.200502688

Article

Identifiers

PID : unige:6898
DOI : 10.1002/anie.200502688
PMID : 16404759

Journal ISSN1433-7851

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Catalytic Enantioselective Hydrogenolysis of [Cr(CO)3(5,8-Dibromonaphthalene)]

Split and run: A study of the asymmetric hydrogenolysis of an aryl-carbon-bromine bond in a naphthalene chromiumtricarbonyl complex shows the use of a new bulky phosphoramidite ligand to yield the product in highly enantiomerically enriched form (see scheme).

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