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Scientific article
English

Catalytic Enantioselective Hydrogenolysis of [Cr(CO)3(5,8-Dibromonaphthalene)]

Published inAngewandte Chemie, vol. 45, no. 7, p. 1092-1095
Publication date2006
Abstract

Split and run: A study of the asymmetric hydrogenolysis of an aryl-carbon-bromine bond in a naphthalene chromiumtricarbonyl complex shows the use of a new bulky phosphoramidite ligand to yield the product in highly enantiomerically enriched form (see scheme).

Keywords
  • Asymmetric synthesis
  • Chromium
  • Hydrogenolysis
  • P ligands
  • Palladium
Citation (ISO format)
KUNDIG, Ernst Peter et al. Catalytic Enantioselective Hydrogenolysis of [Cr(CO)3(5,8-Dibromonaphthalene)]. In: Angewandte Chemie, 2006, vol. 45, n° 7, p. 1092–1095. doi: 10.1002/anie.200502688
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ISSN of the journal1433-7851
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