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Scientific article
English

Choices of iron and copper: cooperative selection during self-assembly

Published inAngewandte Chemie, vol. 45, no. 15, p. 2453-2456
Publication date2006
Abstract

An amicable separation: The reaction between the two aldehydes and amines shown gives initially a dynamic library of 11 imines, which collapses upon the addition of FeII and CuI ions to give only two complexes. The presence of both metals was found to be essential for this selectivity; in particular the thermodynamic stability of the low-spin FeII complex shown was found to play an important role.

Keywords
  • Coordination modes
  • Copper
  • Dynamic combinatorial chemistry
  • Iron
  • Self-assembly
Citation (ISO format)
SCHULTZ, David, NITSCHKE, Jonathan. Choices of iron and copper: cooperative selection during self-assembly. In: Angewandte Chemie, 2006, vol. 45, n° 15, p. 2453–2456. doi: 10.1002/anie.200504447
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ISSN of the journal1433-7851
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