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Title

Rediscovery, isolation, and asymmetric reduction of 1,2,3,4-Tetrahydronaphthalene-1,4-dione and studies of its [Cr(CO)3] complex

Authors
Enríquez García, Alvaro
Published in Angewandte Chemie. 2006, vol. 45, no. 1, p. 98-101
Abstract For 25 years it has been known that 1,4-dihydroxynaphthalene and tetrahydronaphthalene-1,4-dione coexist as stable tautomers; however, the dione has now emerged as an interesting starting material for synthesis. Its efficient isolation is reported, and the corresponding [Cr(CO)3] complexes of the two tautomers are prepared, thus leading to efficient desymmetrization using chiral diamine acyl-transfer catalysts
Keywords AcylationArene ligandsAsymmetric catalysisChromiumKetones
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PMID: 16304647
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KUNDIG, Ernst Peter et al. Rediscovery, isolation, and asymmetric reduction of 1,2,3,4-Tetrahydronaphthalene-1,4-dione and studies of its [Cr(CO)3] complex. In: Angewandte Chemie, 2006, vol. 45, n° 1, p. 98-101. doi: 10.1002/anie.200502588 https://archive-ouverte.unige.ch/unige:6896

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Deposited on : 2010-06-18

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