UNIGE document Scientific Article
previous document  unige:6780  next document
add to browser collection
Title

Asymmetric addition of α-hetero-disubstituted aldehydes to vinyl sulfones; formation of highly functionalized tetrasubstituted carbon centres

Authors
Published in Chemical Communications. 2010, vol. 46, no. 23, p. 4085-4087
Abstract Aminal–pyrrolidine catalysed addition of α-hetero-disubstituted aldehydes to vinyl sulfones is described in high enantioselectivity (ee up to 97%). The obtained adducts can easily be converted to enantioenriched synthons as for example 2,2-dialkylepoxide. Evidence for a kinetic resolution is also observed.
Identifiers
Full text
Article (Published version) (521 Kb) - document accessible for UNIGE members only Limited access to UNIGE
Other version: http://xlink.rsc.org/?DOI=c000326c
Structures
Citation
(ISO format)
QUINTARD, Adrien, ALEXAKIS, Alexandre. Asymmetric addition of α-hetero-disubstituted aldehydes to vinyl sulfones; formation of highly functionalized tetrasubstituted carbon centres. In: Chemical Communications, 2010, vol. 46, n° 23, p. 4085-4087. https://archive-ouverte.unige.ch/unige:6780

193 hits

4 downloads

Update

Deposited on : 2010-06-07

Export document
Format :
Citation style :