UNIGE document Book Chapter
previous document  unige:6722  next document
add to browser collection
Title

Asymmetric organocopper chemistry : Cu-catalyzed conjugate addition and allylic substitution

Author
Published in Malhotra, S.V. Methodologies in Asymmetric Catalysis. Washington: American Chemical Society. 2004, p. 43-59
Collection ACS Symposium Series; 880
Abstract This review deals with the most recent developments in the asymmetric conjugate addition and allylic substitution. For the conjugate addition, the best enantioselectivities (>99%) have been attained with dialkylzinc reagents and 0.5-2% CuX and 1-4% of a chiral trivalent phosphorus ligand. The γ-allylic substitution can be achieved equally well with, either dialkylzinc or Grignard reagents, and the same catalysts.
Identifiers
ISBN: 978-0-8412-3835-0
Full text
Book chapter (58 Kb) - public document Free access
Structures
Citation
(ISO format)
ALEXAKIS, Alexandre. Asymmetric organocopper chemistry : Cu-catalyzed conjugate addition and allylic substitution. In: Malhotra, S.V. (Ed.). Methodologies in Asymmetric Catalysis. Washington : American Chemical Society, 2004. p. 43-59. (ACS Symposium Series; 880) https://archive-ouverte.unige.ch/unige:6722

192 hits

685 downloads

Update

Deposited on : 2010-05-28

Export document
Format :
Citation style :