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Scientific article
English

Asymmetric Diels—Alder Reactions Catalyzed by a Chiral Iron Lewis Acid

Published inAngewandte Chemie. International edition in English, vol. 33, no. 18, p. 1856-1858
Publication date1994
Abstract

A substitute for the CO ligand in the form of an electron-poor, chiral phosphorus ligand can be used to synthesize efficient transition-metal catalysts for asymmetric Diels - Alder reactions. In the presence of 2, for example, a-bromoacrolein reacts with cyclohexadiene to form 1 in > 99% ee.

NoteParu également dans Angewandte Chemie sous le titre:"Durch eine chirale Eisen-Lewis-Säure katalysierte asymmetrische Diels-Alder-Reaktionen" en 1994, 106(18), 1931-1934
Citation (ISO format)
KUNDIG, Ernst Peter, BOURDIN, Bernadette, BERNARDINELLI, Gérald Hugues. Asymmetric Diels—Alder Reactions Catalyzed by a Chiral Iron Lewis Acid. In: Angewandte Chemie. International edition in English, 1994, vol. 33, n° 18, p. 1856–1858. doi: 10.1002/anie.199418561
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ISSN of the journal0570-0833
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