Additions of Carbanions to a Cationic Cyclopentadienyl(naphthalene)iron Complex

Kundig, Ernst Peter; Jeger, Patrick; Bernardinelli, Gérald Hugues

doi:10.1002/anie.199521611

Scientific article

English

Additions of Carbanions to a Cationic Cyclopentadienyl(naphthalene)iron Complex

ContributorsKundig, Ernst Peter; Jeger, Patrick; Bernardinelli, Gérald Hugues

Published inAngewandte Chemie. International edition in English, vol. 34, no. 19, p. 2161-2163

Publication date1995

Abstract

A simple change in the substitution pattern of the naphthalene ligand can effectively alter the reaction pathway: the reaction of [Cp(naphthalene)Fe]PF6 with carbon nucleophiles results in reduction of the Fe center, but complex 1 reacts with PhLi by nucleophilic addition at the condensed arene. When tBuLi is used as the nucleophile, addition to the Cp ring of 1 giving 2 is observed instead.

Keywords

Arene complexes
Iron compounds
Haptotropic rearrangements
Nucleophilic additions

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

KUNDIG, Ernst Peter, JEGER, Patrick, BERNARDINELLI, Gérald Hugues. Additions of Carbanions to a Cationic Cyclopentadienyl(naphthalene)iron Complex. In: Angewandte Chemie. International edition in English, 1995, vol. 34, n° 19, p. 2161–2163. doi: 10.1002/anie.199521611

Identifiers

PID : unige:6663
DOI : 10.1002/anie.199521611

Journal ISSN0570-0833

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Additions of Carbanions to a Cationic Cyclopentadienyl(naphthalene)iron Complex

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