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Additions of Carbanions to a Cationic Cyclopentadienyl(naphthalene)iron Complex
|Published in||Angewandte Chemie: International Edition in English. 1995, vol. 34, no. 19, p. 2161 - 2163|
|Abstract||A simple change in the substitution pattern of the naphthalene ligand can effectively alter the reaction pathway: the reaction of [Cp(naphthalene)Fe]PF6 with carbon nucleophiles results in reduction of the Fe center, but complex 1 reacts with PhLi by nucleophilic addition at the condensed arene. When tBuLi is used as the nucleophile, addition to the Cp ring of 1 giving 2 is observed instead.|
|Keywords||Arene complexes — Iron compounds — Haptotropic rearrangements — Nucleophilic additions|
|KUNDIG, Ernst Peter, JEGER, Patrick, BERNARDINELLI, Gérald Hugues. Additions of Carbanions to a Cationic Cyclopentadienyl(naphthalene)iron Complex. In: Angewandte Chemie: International Edition in English, 1995, vol. 34, n° 19, p. 2161 - 2163. https://archive-ouverte.unige.ch/unige:6663|