New Chromium Carbonyl Catalysts for [6+2] Cycloaddition Reactions

Kundig, Ernst Peter; Robvieux, Fabrice; Kondratenko, Mikhail

doi:10.1055/s-2002-34393

Scientific article

English

New Chromium Carbonyl Catalysts for [6+2] Cycloaddition Reactions

ContributorsKundig, Ernst Peter; Robvieux, Fabrice; Kondratenko, Mikhail

Published inSynthesis, no. 14, no. 14 (Sp. Iss.), p. 2053-2056

Publication date2002

Abstract

The complexes, (benzene)chromiumdicarbonyl(methyl acrylate) and chromiumdicarbonylbis(cyclohexadiene), are precursors for the highly coordinatively unsaturated chromium dicarbonyl fragment 3, a catalyst for the cycloaddition of activated olefins to cycloheptatriene.

Keywords

(arene)Cr(CO)3 Complexes
Higher order cycloaddition
Acrylate
Diene chromium complex

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

KUNDIG, Ernst Peter, ROBVIEUX, Fabrice, KONDRATENKO, Mikhail. New Chromium Carbonyl Catalysts for [6+2] Cycloaddition Reactions. In: Synthesis, 2002, n° 14, p. 2053–2056. doi: 10.1055/s-2002-34393

Identifiers

PID : unige:6610
DOI : 10.1055/s-2002-34393

Journal ISSN0039-7881

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New Chromium Carbonyl Catalysts for [6+2] Cycloaddition Reactions

The complexes, (benzene)chromiumdicarbonyl(methyl acrylate) and chromiumdicarbonylbis(cyclohexadiene), are precursors for the highly coordinatively unsaturated chromium dicarbonyl fragment 3, a catalyst for the cycloaddition of activated olefins to cycloheptatriene.

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