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New Chromium Carbonyl Catalysts for [6+2] Cycloaddition Reactions

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Published in Synthesis. 2002, no. 14, p. 2053 - 2056
Abstract The complexes, (benzene)chromiumdicarbonyl(methyl acrylate) and chromiumdicarbonylbis(cyclohexadiene), are precursors for the highly coordinatively unsaturated chromium dicarbonyl fragment 3, a catalyst for the cycloaddition of activated olefins to cycloheptatriene.
Keywords (arene)Cr(CO)3 ComplexesHigher order cycloadditionAcrylateDiene chromium complex
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KUNDIG, Ernst Peter, ROBVIEUX, Fabrice, KONDRATENKO, Mikhail. New Chromium Carbonyl Catalysts for [6+2] Cycloaddition Reactions. In: Synthesis, 2002, n° 14, p. 2053 - 2056. https://archive-ouverte.unige.ch/unige:6610

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Deposited on : 2010-05-17

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