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Kinetic studies on the photochemically activated solvation of[(.eta.6-arene1)Ru(.eta.6-arene2)]2+ Sandwich compounds

Authors
Karlen, Thomas
Ludi, Andreas
Published in Inorganic Chemistry. 1994, vol. 33, no. 10, p. 2213 - 2218
Abstract Irradiation of the inert complexes ((η6-arene1)Ru(η6-arene2)]2+ (arene=benzene, toluene, mesitylene, hexamethylbenzene, anisole, biphenyl, naphthalene, chrysene) in various solvents (H2O/H+, H2O/H+/EtOH, acetonitrile, DMSO) leads to the fully solvated complexes (Ru(solvent)6]2+. The reaction occurs in two consecutive steps. The first step is the formation of the intermediate ((η6-arene)Ru(solvent)3]2+ with either arene1 or arene2 being replaced by solvent.
Keywords Organic ligandSolvationSandwich compoundCationic complexTolueneHapto complexPhotolysisQuantum yieldHueckel methodRuthenium ComplexesTransition metal ComplexesPlatinoid Complexes
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KARLEN, Thomas, HAUSER, Andreas, LUDI, Andreas. Kinetic studies on the photochemically activated solvation of[(.eta.6-arene1)Ru(.eta.6-arene2)]2+ Sandwich compounds. In: Inorganic Chemistry, 1994, vol. 33, n° 10, p. 2213 - 2218. https://archive-ouverte.unige.ch/unige:6512

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Deposited on : 2010-05-04

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