Kinetic studies on the photochemically activated solvation of[(.eta.6-arene1)Ru(.eta.6-arene2)]2+ Sandwich compounds

Karlen, Thomas; Hauser, Andreas; Ludi, Andreas

doi:10.1021/ic00088a025

Article scientifique

Anglais

Kinetic studies on the photochemically activated solvation of[(.eta.6-arene1)Ru(.eta.6-arene2)]2+ Sandwich compounds

Contributeurs/tricesKarlen, Thomas; Hauser, Andreas; Ludi, Andreas

Publié dansInorganic chemistry, vol. 33, no. 10, p. 2213-2218

Date de publication1994

Résumé

Irradiation of the inert complexes ((η6-arene1)Ru(η6-arene2)]2+ (arene=benzene, toluene, mesitylene, hexamethylbenzene, anisole, biphenyl, naphthalene, chrysene) in various solvents (H2O/H+, H2O/H+/EtOH, acetonitrile, DMSO) leads to the fully solvated complexes (Ru(solvent)6]2+. The reaction occurs in two consecutive steps. The first step is the formation of the intermediate ((η6-arene)Ru(solvent)3]2+ with either arene1 or arene2 being replaced by solvent.

Mots-clés

Organic ligand
Solvation
Sandwich compound
Cationic complex
Toluene
Hapto complex
Photolysis
Quantum yield
Hueckel method
Ruthenium Complexes
Transition metal Complexes
Platinoid Complexes

Structure d'affiliation Pas une publication de l'UNIGE

Citation (format ISO)

KARLEN, Thomas, HAUSER, Andreas, LUDI, Andreas. Kinetic studies on the photochemically activated solvation of[(.eta.6-arene1)Ru(.eta.6-arene2)]2+ Sandwich compounds. In: Inorganic chemistry, 1994, vol. 33, n° 10, p. 2213–2218. doi: 10.1021/ic00088a025

Article (Published version)

Identifiants

PID : unige:6512
DOI : 10.1021/ic00088a025

ISSN du journal0020-1669

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Kinetic studies on the photochemically activated solvation of[(.eta.6-arene1)Ru(.eta.6-arene2)]2+ Sandwich compounds

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