Kinetic studies on the photochemically activated solvation of[(.eta.6-arene1)Ru(.eta.6-arene2)]2+ Sandwich compounds

Karlen, Thomas; Hauser, Andreas; Ludi, Andreas

doi:10.1021/ic00088a025

Scientific article

English

Kinetic studies on the photochemically activated solvation of[(.eta.6-arene1)Ru(.eta.6-arene2)]2+ Sandwich compounds

ContributorsKarlen, Thomas; Hauser, Andreas; Ludi, Andreas

Published inInorganic chemistry, vol. 33, no. 10, p. 2213-2218

Publication date1994

Abstract

Irradiation of the inert complexes ((η6-arene1)Ru(η6-arene2)]2+ (arene=benzene, toluene, mesitylene, hexamethylbenzene, anisole, biphenyl, naphthalene, chrysene) in various solvents (H2O/H+, H2O/H+/EtOH, acetonitrile, DMSO) leads to the fully solvated complexes (Ru(solvent)6]2+. The reaction occurs in two consecutive steps. The first step is the formation of the intermediate ((η6-arene)Ru(solvent)3]2+ with either arene1 or arene2 being replaced by solvent.

Keywords

Organic ligand
Solvation
Sandwich compound
Cationic complex
Toluene
Hapto complex
Photolysis
Quantum yield
Hueckel method
Ruthenium Complexes
Transition metal Complexes
Platinoid Complexes

Affiliation entities

Not a UNIGE publication

Citation (ISO format)

KARLEN, Thomas, HAUSER, Andreas, LUDI, Andreas. Kinetic studies on the photochemically activated solvation of[(.eta.6-arene1)Ru(.eta.6-arene2)]2+ Sandwich compounds. In: Inorganic chemistry, 1994, vol. 33, n° 10, p. 2213–2218. doi: 10.1021/ic00088a025

Article (Published version)

Identifiers

PID : unige:6512
DOI : 10.1021/ic00088a025

Journal ISSN0020-1669

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Kinetic studies on the photochemically activated solvation of[(.eta.6-arene1)Ru(.eta.6-arene2)]2+ Sandwich compounds

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