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Scientific article
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An electrochemical and photophysical study of a covalently linked inorganic-organic dyad

Published inChemPhysChem, vol. 11, no. 3, p. 651-658
Publication date2010
Abstract

A molecular donor-acceptor dyad comprising a hexarhenium cluster core, [Re6(3-Se)8]2+, and a fullerene moiety which are covalently linked through a pyridine ligand was synthesized and fully characterized. The electrochemical and photophysical properties are reported. The detailed study includes cyclic voltammetry, steady-state absorption and fluorescence spectroscopy, radiation chemistry and transient absorption spectroscopy. A light-induced electron transfer between the inorganic cluster moiety and the fullerene can be excluded. However, a light-induced energy transfer from the rhenium cluster to the fullerene is proposed.

Keywords
  • Cluster compounds
  • Cyclic voltammetry
  • Energy transfer
  • Fullerenes
  • Radiation chemistry
Citation (ISO format)
KAHNT, Axel et al. An electrochemical and photophysical study of a covalently linked inorganic-organic dyad. In: ChemPhysChem, 2010, vol. 11, n° 3, p. 651–658. doi: 10.1002/cphc.200900728
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ISSN of the journal1439-4235
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