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Scientific article
English

Copper-catalyzed asymmetric β-boration of α,β-unsaturated carbonyl derivatives

Published inChemCatChem, vol. 2, no. 5, p. 501-504
Publication date2010
Abstract

The β generation: Transition metal- catalyzed asymmetric β-boration of α,β- unsaturated carbonyl derivatives has recently received much attention. Although a variety of metals can be used to promote this reaction, copper has recently emerged as the candidate of choice. Given the appropriate chiral ligand and reaction conditions, the challenging β-boration of β,β-disubstituted cyclic enones is achieved with excellent yields and enantioselectivities.

Keywords
  • Asymmetric catalysis
  • Boration
  • Conjugate addition
  • Copper
  • Carbonyl compounds
Citation (ISO format)
MANTILLI, Luca, MAZET, Clement. Copper-catalyzed asymmetric β-boration of α,β-unsaturated carbonyl derivatives. In: ChemCatChem, 2010, vol. 2, n° 5, p. 501–504. doi: 10.1002/cctc.201000008
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Article (Published version)
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Identifiers
ISSN of the journal1867-3899
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Creation04/30/2010 10:13:00 AM
First validation04/30/2010 10:13:00 AM
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