en
Scientific article
English

ω-ethylenic allylic substrates as alternatives to cyclic substrates in copper- and iridium-catalyzed asymmetric allylic alkylation

Published inOrganic letters, vol. 12, no. 6, p. 1156-1159
Publication date2010
Abstract

A new strategy to access highly enantioenriched cyclic compounds (up to 98%) is proposed using ω-ethylenic allylic substrates through a one-pot asymmetric allylic alkylation and ring-closing metathesis. Such starting compounds can be seen as synthetic equivalents of cyclic allylic substrates.

Citation (ISO format)
GIACOMINA, Francesca, RIAT, David, ALEXAKIS, Alexandre. ω-ethylenic allylic substrates as alternatives to cyclic substrates in copper- and iridium-catalyzed asymmetric allylic alkylation. In: Organic letters, 2010, vol. 12, n° 6, p. 1156–1159. doi: 10.1021/ol100162y
Main files (1)
Article (Published version)
accessLevelRestricted
Identifiers
ISSN of the journal1523-7052
558views
0downloads

Technical informations

Creation04/26/2010 10:09:00 AM
First validation04/26/2010 10:09:00 AM
Update time03/14/2023 3:28:16 PM
Status update03/14/2023 3:28:16 PM
Last indexation01/15/2024 7:54:16 PM
All rights reserved by Archive ouverte UNIGE and the University of GenevaunigeBlack