Scientific article
English

ω-ethylenic allylic substrates as alternatives to cyclic substrates in copper- and iridium-catalyzed asymmetric allylic alkylation

Published inOrganic letters, vol. 12, no. 6, p. 1156-1159
Publication date2010
Abstract

A new strategy to access highly enantioenriched cyclic compounds (up to 98%) is proposed using ω-ethylenic allylic substrates through a one-pot asymmetric allylic alkylation and ring-closing metathesis. Such starting compounds can be seen as synthetic equivalents of cyclic allylic substrates.

Citation (ISO format)
GIACOMINA, Francesca, RIAT, David, ALEXAKIS, Alexandre. ω-ethylenic allylic substrates as alternatives to cyclic substrates in copper- and iridium-catalyzed asymmetric allylic alkylation. In: Organic letters, 2010, vol. 12, n° 6, p. 1156–1159. doi: 10.1021/ol100162y
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Journal ISSN1523-7052
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