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ω-ethylenic allylic substrates as alternatives to cyclic substrates in copper- and iridium-catalyzed asymmetric allylic alkylation

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Riat, David
Published in Organic Letters. 2010, vol. 12, no. 6, p. 1156 - 1159
Abstract A new strategy to access highly enantioenriched cyclic compounds (up to 98%) is proposed using ω-ethylenic allylic substrates through a one-pot asymmetric allylic alkylation and ring-closing metathesis. Such starting compounds can be seen as synthetic equivalents of cyclic allylic substrates.
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GIACOMINA, Francesca, RIAT, David, ALEXAKIS, Alexandre. ω-ethylenic allylic substrates as alternatives to cyclic substrates in copper- and iridium-catalyzed asymmetric allylic alkylation. In: Organic Letters, 2010, vol. 12, n° 6, p. 1156 - 1159. https://archive-ouverte.unige.ch/unige:6362

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Deposited on : 2010-04-26

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