Synthèse stéréospécifique d'oléfines di- et trisubstituées par alcoylation des vinyl cuivres

Normant, Jean F.; Cahiez, Gerard; Chuit, Claude; Alexakis, Alexandre; Villieras, Jean

doi:10.1016/S0022-328X(00)86981-8

Scientific article

French

Synthèse stéréospécifique d'oléfines di- et trisubstituées par alcoylation des vinyl cuivres

ContributorsNormant, Jean F.; Cahiez, Gerard; Chuit, Claude; Alexakis, Alexandre; Villieras, Jean

Published inJournal of organometallic chemistry, vol. 40, no. 1, p. C49-C52

Publication date1972

Abstract

Stereospecifically prepared vinylic organocopper reagents have been alkylated, in the presence of triethylphosphite and hexamethylphosphotriamide, with retention of configuration. A new method of synthesising stereospecific trisubstituted alkenes is achieved.

Affiliation Not a UNIGE publication

Citation (ISO format)

NORMANT, Jean F. et al. Synthèse stéréospécifique d’oléfines di- et trisubstituées par alcoylation des vinyl cuivres. In: Journal of organometallic chemistry, 1972, vol. 40, n° 1, p. C49–C52. doi: 10.1016/S0022-328X(00)86981-8

Article (Published version)

Identifiers

PID : unige:6316
DOI : 10.1016/S0022-328X(00)86981-8

ISSN of the journal0022-328X

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Synthèse stéréospécifique d'oléfines di- et trisubstituées par alcoylation des vinyl cuivres

Stereospecifically prepared vinylic organocopper reagents have been alkylated, in the presence of triethylphosphite and hexamethylphosphotriamide, with retention of configuration. A new method of synthesising stereospecific trisubstituted alkenes is achieved.

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