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Matrix isolation laser Raman spectroscopy: a Raman and infrared spectral study including Raman polarisation data for the co-condensation reaction of Pd Spectroscopic and structural data for the new tetra-carbonyls Pd(CO)4 AND Pt(CO)4

Published inJournal of molecular structure, vol. 14, no. 1, p. 137-144
Publication date1972
Abstract

The chemical species formed in the co-condensation reactions of Pd and Pt atoms with CO at 4.2–10 °K are investigated for the first time using the combined techniques of matrix isolation infrared and laser Raman spectroscopy. Under these experimental conditions the spectroscopic data show that one major product is formed. The data when taken in conjunction with the depolarisation measurements for the matrix isolated species confirms the existence in the matrix of the previously unknown tetracarbonyls Pd(CO)4 and Pt(CO)4 both having Td symmetry. Cotton-Kraihanzel force constants are calculated for the series M(CO)4 where M = Ni, Pd and Pt.

Affiliation Not a UNIGE publication
Citation (ISO format)
KUNDIG, Ernst Peter, MOSKOVITS, M., OZIN, G.A. Matrix isolation laser Raman spectroscopy: a Raman and infrared spectral study including Raman polarisation data for the co-condensation reaction of Pd Spectroscopic and structural data for the new tetra-carbonyls Pd(CO)4 AND Pt(CO)4. In: Journal of molecular structure, 1972, vol. 14, n° 1, p. 137–144. doi: 10.1016/0022-2860(72)80063-2
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ISSN of the journal0022-2860
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