On the mechanism of the thermal naphthalene automerization, a comment

Burger, Ulrich; Mareda, Jiri

doi:10.1016/S0040-4039(00)99833-2

Scientific article

Letter

English

On the mechanism of the thermal naphthalene automerization, a comment

ContributorsBurger, Ulrich; Mareda, Jiri

Published inTetrahedron letters, vol. 25, no. 2, p. 177-180

Publication date1984

Abstract

The title reaction is suggested to proceed by a reversible valence isomerization via a laterally bridge benzvalene (2). No analogous behaviour is expected for pyrene.

Affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

BURGER, Ulrich, MAREDA, Jiri. On the mechanism of the thermal naphthalene automerization, a comment. In: Tetrahedron letters, 1984, vol. 25, n° 2, p. 177–180. doi: 10.1016/S0040-4039(00)99833-2

Article (Published version)

Identifiers

PID : unige:6238
DOI : 10.1016/S0040-4039(00)99833-2

ISSN of the journal0040-4039

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On the mechanism of the thermal naphthalene automerization, a comment

The title reaction is suggested to proceed by a reversible valence isomerization via a laterally bridge benzvalene (2). No analogous behaviour is expected for pyrene.

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