Steric effects on reaction rates - V. An updated version of the foote-schleyer correlation based on molecular mechanics
|Published in||Tetrahedron Letters. 1984, vol. 25, no. 16, p. 1703-1706|
|Abstract||The strain changes occurring during solvolysis of secondary tosylates are calculated by a molecular mechanics programme (MM2) using an empirical force-field for carbenium ions. The rate constants for acetolysis of kC-substrates correlate with these strain changes, defining a straight line representative for kC behaviour.|
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|MULLER, Paul, MAREDA, Jiri. Steric effects on reaction rates - V. An updated version of the foote-schleyer correlation based on molecular mechanics. In: Tetrahedron Letters, 1984, vol. 25, n° 16, p. 1703-1706. https://archive-ouverte.unige.ch/unige:6237|