Steric effects on reaction rates - V. An updated version of the Foote-Schleyer correlation based on molecular mechanics

Muller, Paul; Mareda, Jiri

doi:10.1016/S0040-4039(01)81149-7

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Steric effects on reaction rates - V. An updated version of the Foote-Schleyer correlation based on molecular mechanics

Contributeurs/tricesMuller, Paul; Mareda, Jiri

Publié dansTetrahedron letters, vol. 25, no. 16, p. 1703-1706

Date de publication1984

Résumé

The strain changes occurring during solvolysis of secondary tosylates are calculated by a molecular mechanics programme (MM2) using an empirical force-field for carbenium ions. The rate constants for acetolysis of k_C-substrates correlate with these strain changes, defining a straight line representative for k_C behaviour.

Structure d'affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (format ISO)

MULLER, Paul, MAREDA, Jiri. Steric effects on reaction rates - V. An updated version of the Foote-Schleyer correlation based on molecular mechanics. In: Tetrahedron letters, 1984, vol. 25, n° 16, p. 1703–1706. doi: 10.1016/S0040-4039(01)81149-7

Article (Published version)

Identifiants

PID : unige:6237
DOI : 10.1016/S0040-4039(01)81149-7

ISSN du journal0040-4039

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Steric effects on reaction rates - V. An updated version of the Foote-Schleyer correlation based on molecular mechanics

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