Steric effects on reaction rates - V. An updated version of the Foote-Schleyer correlation based on molecular mechanics

Muller, Paul; Mareda, Jiri

doi:10.1016/S0040-4039(01)81149-7

Scientific article

Letter

English

Steric effects on reaction rates - V. An updated version of the Foote-Schleyer correlation based on molecular mechanics

ContributorsMuller, Paul; Mareda, Jiri

Published inTetrahedron letters, vol. 25, no. 16, p. 1703-1706

Publication date1984

Abstract

The strain changes occurring during solvolysis of secondary tosylates are calculated by a molecular mechanics programme (MM2) using an empirical force-field for carbenium ions. The rate constants for acetolysis of k_C-substrates correlate with these strain changes, defining a straight line representative for k_C behaviour.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

MULLER, Paul, MAREDA, Jiri. Steric effects on reaction rates - V. An updated version of the Foote-Schleyer correlation based on molecular mechanics. In: Tetrahedron letters, 1984, vol. 25, n° 16, p. 1703–1706. doi: 10.1016/S0040-4039(01)81149-7

Article (Published version)

Identifiers

PID : unige:6237
DOI : 10.1016/S0040-4039(01)81149-7

Journal ISSN0040-4039

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Steric effects on reaction rates - V. An updated version of the Foote-Schleyer correlation based on molecular mechanics

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