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Scientific article
Letter
English

Steric effects on reaction rates - V. An updated version of the Foote-Schleyer correlation based on molecular mechanics

Published inTetrahedron letters, vol. 25, no. 16, p. 1703-1706
Publication date1984
Abstract

The strain changes occurring during solvolysis of secondary tosylates are calculated by a molecular mechanics programme (MM2) using an empirical force-field for carbenium ions. The rate constants for acetolysis of kC-substrates correlate with these strain changes, defining a straight line representative for kC behaviour.

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Citation (ISO format)
MULLER, Paul, MAREDA, Jiri. Steric effects on reaction rates - V. An updated version of the Foote-Schleyer correlation based on molecular mechanics. In: Tetrahedron letters, 1984, vol. 25, n° 16, p. 1703–1706. doi: 10.1016/S0040-4039(01)81149-7
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ISSN of the journal0040-4039
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