The transformation of difluorocarbene into 3,3-diflurocyclopropene

Jefford, Charles; Acar, Mehmet; Delay, Arlette; Mareda, Jiri; Burger, Ulrich

doi:10.1016/S0040-4039(01)86877-5

Scientific article

Letter

English

The transformation of difluorocarbene into 3,3-diflurocyclopropene

ContributorsJefford, Charles; Acar, Mehmet; Delay, Arlette; Mareda, Jiri; Burger, Ulrich

Published inTetrahedron letters, vol. 20, no. 21, p. 1913-1916

Publication date1979

Abstract

The addition of difluorocarbene to benzobarrelene gives the syn and anti 1,2 mono-adducts. Heating of either of them at 200°C in hexadeuteriobenzene generates naphthalene and 3,3-difluorocyclopropene.

Affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

JEFFORD, Charles et al. The transformation of difluorocarbene into 3,3-diflurocyclopropene. In: Tetrahedron letters, 1979, vol. 20, n° 21, p. 1913–1916. doi: 10.1016/S0040-4039(01)86877-5

Identifiers

PID : unige:6234
DOI : 10.1016/S0040-4039(01)86877-5

ISSN of the journal0040-4039

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The transformation of difluorocarbene into 3,3-diflurocyclopropene

The addition of difluorocarbene to benzobarrelene gives the syn and anti 1,2 mono-adducts. Heating of either of them at 200°C in hexadeuteriobenzene generates naphthalene and 3,3-difluorocyclopropene.

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