The Synthesis and Structure of Pentacarbonyl (5H-dipyrrolo[1,2-c: 2',1'-e]imidazol-5-yl)manganese

Burger, Ulrich; Perret, Celia; Bernardinelli, Gérald Hugues; Kundig, Ernst Peter

doi:10.1002/hlca.19840670806

Scientific article

English

The Synthesis and Structure of Pentacarbonyl (5H-dipyrrolo[1,2-c: 2',1'-e]imidazol-5-yl)manganese

ContributorsBurger, Ulrich; Perret, Celia; Bernardinelli, Gérald Hugues; Kundig, Ernst Peter

Published inHelvetica chimica acta, vol. 67, no. 8, p. 2063-2067

Publication date1984

Abstract

The dipyrroloimidazolyl ligand is found to bind the pentacarbonylmanganese group to its central ring via a carbon-metal -bond. This bonding mode differs greatly from that of known imidazole complexes and from the pentahapto mode encountered with the isoelectronic fluorenyl ligand. The X-ray structure of the title compound is reported.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

BURGER, Ulrich et al. The Synthesis and Structure of Pentacarbonyl (5H-dipyrrolo[1,2-c: 2′,1′-e]imidazol-5-yl)manganese. In: Helvetica chimica acta, 1984, vol. 67, n° 8, p. 2063–2067. doi: 10.1002/hlca.19840670806

Article (Published version)

Identifiers

PID : unige:6216
DOI : 10.1002/hlca.19840670806

Journal ISSN0018-019X

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The Synthesis and Structure of Pentacarbonyl (5H-dipyrrolo[1,2-c: 2',1'-e]imidazol-5-yl)manganese

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