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The Synthesis and Structure of Pentacarbonyl (5H-dipyrrolo[1,2-c: 2',1'-e]imidazol-5-yl)manganese

Perret, Celia
Published in Helvetica Chimica Acta. 1984, vol. 67, no. 8, p. 2063-2067
Abstract The dipyrroloimidazolyl ligand is found to bind the pentacarbonylmanganese group to its central ring via a carbon-metal -bond. This bonding mode differs greatly from that of known imidazole complexes and from the pentahapto mode encountered with the isoelectronic fluorenyl ligand. The X-ray structure of the title compound is reported.
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BURGER, Ulrich et al. The Synthesis and Structure of Pentacarbonyl (5H-dipyrrolo[1,2-c: 2',1'-e]imidazol-5-yl)manganese. In: Helvetica Chimica Acta, 1984, vol. 67, n° 8, p. 2063-2067. doi: 10.1002/hlca.19840670806 https://archive-ouverte.unige.ch/unige:6216

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Deposited on : 2010-04-20

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