A New Chiral Ligand for the Fe-Lewis Acid Catalysed Asymmetric Diels-Alder Reaction

Bruin, Marion Evelyn; Kundig, Ernst Peter

doi:10.1039/a806445h

Scientific article

English

A New Chiral Ligand for the Fe-Lewis Acid Catalysed Asymmetric Diels-Alder Reaction

ContributorsBruin, Marion Evelyn; Kundig, Ernst Peter

Published inChemical communications, vol. 33, no. 23, p. 2635-2636

Publication date1998

Abstract

The readily accessible enantiopure hydrobenzoin forms the backbone of the new bidentate ligand BIPHOP-F that is shown here to provide the chiral environment for a highly enantioselective Fe–Lewis acid catalysed Diels–Alder reaction between α,β-enals and dienes.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

BRUIN, Marion Evelyn, KUNDIG, Ernst Peter. A New Chiral Ligand for the Fe-Lewis Acid Catalysed Asymmetric Diels-Alder Reaction. In: Chemical communications, 1998, vol. 33, n° 23, p. 2635–2636. doi: 10.1039/a806445h

Identifiers

PID : unige:6203
DOI : 10.1039/a806445h

Journal ISSN1359-7345

891views

0downloads

Creation20/04/2010 12:09:36

First validation20/04/2010 12:09:36

Update time14/03/2023 16:27:45

Status update14/03/2023 16:27:45

Last indexation29/10/2024 15:33:29

Archive ouverte UNIGE

A New Chiral Ligand for the Fe-Lewis Acid Catalysed Asymmetric Diels-Alder Reaction

The readily accessible enantiopure hydrobenzoin forms the backbone of the new bidentate ligand BIPHOP-F that is shown here to provide the chiral environment for a highly enantioselective Fe–Lewis acid catalysed Diels–Alder reaction between α,β-enals and dienes.

Technical informations