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Intramolecular Pd Catalyzed Carbocyclization Reactions with Planar Chiral Arene Tricarbonyl Chromium Complexes

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Xu, Long He
Published in Synlett. 1998, no. 6, p. 658-660
Abstract ortho-Butenylchlorobenzene tricarbonylchromium complexes undergo intramolecular Pd catalyzed cyclizations (Heck-reactions) without decomplexation and/or alkene isomerization. The diastereoselectivity of the alkene carbopalladation is governed by the planar chirality of the complex.
Keywords Heck-reactionPlanar chiralityArene complexChromium
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CROUSSE, Benoît et al. Intramolecular Pd Catalyzed Carbocyclization Reactions with Planar Chiral Arene Tricarbonyl Chromium Complexes. In: Synlett, 1998, n° 6, p. 658-660. https://archive-ouverte.unige.ch/unige:6198

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Deposited on : 2010-04-20

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