Intramolecular Pd Catalyzed Carbocyclization Reactions with Planar Chiral Arene Tricarbonyl Chromium Complexes

Crousse, Benoît; Xu, Long He; Bernardinelli, Gérald Hugues; Kundig, Ernst Peter

doi:10.1055/s-1998-1722

Scientific article

English

Intramolecular Pd Catalyzed Carbocyclization Reactions with Planar Chiral Arene Tricarbonyl Chromium Complexes

ContributorsCrousse, Benoît; Xu, Long He; Bernardinelli, Gérald Hugues; Kundig, Ernst Peter

Published inSynlett, no. 6, p. 658-660

Publication date1998

Abstract

ortho-Butenylchlorobenzene tricarbonylchromium complexes undergo intramolecular Pd catalyzed cyclizations (Heck-reactions) without decomplexation and/or alkene isomerization. The diastereoselectivity of the alkene carbopalladation is governed by the planar chirality of the complex.

Keywords

Heck-reaction
Planar chirality
Arene complex
Chromium

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

CROUSSE, Benoît et al. Intramolecular Pd Catalyzed Carbocyclization Reactions with Planar Chiral Arene Tricarbonyl Chromium Complexes. In: Synlett, 1998, n° 6, p. 658–660. doi: 10.1055/s-1998-1722

Identifiers

PID : unige:6198
DOI : 10.1055/s-1998-1722

Journal ISSN0936-5214

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Intramolecular Pd Catalyzed Carbocyclization Reactions with Planar Chiral Arene Tricarbonyl Chromium Complexes

ortho-Butenylchlorobenzene tricarbonylchromium complexes undergo intramolecular Pd catalyzed cyclizations (Heck-reactions) without decomplexation and/or alkene isomerization. The diastereoselectivity of the alkene carbopalladation is governed by the planar chirality of the complex.

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