UNIGE document Scientific Article
previous document  unige:6197  next document
add to browser collection
Title

Planar Chiral Tricarbonylchromium Complexes: Asymmetric Aza-Diels-Alder Reaction and Intramolecular Radical Cyclization to Indolizidines and Quinolizidines

Authors
Xu, Long He
Published in Synlett. 1996, no. 3, p. 270-272
Abstract Highly diastereoselective Lewis acid mediated aza-Diels-Alder reactions of planar chiral Cr(CO)3 complexes of o-substituted benzaldehyde imines are reported. Enantio- and diastereopure complexes of 2-aryl-2,3-dihydro-4-pyridinones obtained via this route undergo intramolecular radical cyclization to the title compounds with complete diastereoselectivity.
Keywords Hetero Diels-Alder reactionPlanar chiralityArene complexChromium radical cyclization
Identifiers
Full text
This document has no fulltext available yet, but you can contact its author by using the form below.
Structures
Citation
(ISO format)
KUNDIG, Ernst Peter et al. Planar Chiral Tricarbonylchromium Complexes: Asymmetric Aza-Diels-Alder Reaction and Intramolecular Radical Cyclization to Indolizidines and Quinolizidines. In: Synlett, 1996, n° 3, p. 270-272. https://archive-ouverte.unige.ch/unige:6197

213 hits

0 download

Update

Deposited on : 2010-04-20

Export document
Format :
Citation style :