Planar Chiral Arylaldehydeimine Tricarbonylchromium Complexes in the Asymmetric Baylis-Hillman Coupling Reaction

Kundig, Ernst Peter; Xu, Long He; Schnell, Barbara

doi:10.1055/s-1994-22869

Scientific article

English

Planar Chiral Arylaldehydeimine Tricarbonylchromium Complexes in the Asymmetric Baylis-Hillman Coupling Reaction

Contributors

Kundig, Ernst Peter; Xu, Long He; Schnell, Barbara

Published in

Synlett, no. 6, p. 413-414

Publication date

1994

Abstract

The DABCO-catalyzed coupling reaction of methyl acrylate and acrylonitrile with enantiomerically pure planar chiral o-substituted (benzaldehyde tosylimine) Cr(CO)3 complexes after metal removal provides chiral amines in high yields and enantiomeric excess.

UNIGE affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

KUNDIG, Ernst Peter, XU, Long He, SCHNELL, Barbara. Planar Chiral Arylaldehydeimine Tricarbonylchromium Complexes in the Asymmetric Baylis-Hillman Coupling Reaction. In: Synlett, 1994, n° 6, p. 413–414. doi: 10.1055/s-1994-22869

Identifiers

PID : unige:6196
DOI : 10.1055/s-1994-22869

Journal ISSN

0936-5214

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20/04/2010 10:09:33

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20/04/2010 10:09:33

Update

14/03/2023 15:27:44

Status update

14/03/2023 15:27:44

Last indexation

29/10/2024 14:33:22

Planar Chiral Arylaldehydeimine Tricarbonylchromium Complexes in the Asymmetric Baylis-Hillman Coupling Reaction

Contributors

Published in

Publication date

Abstract

UNIGE affiliation entities

Citation (ISO format)

Identifiers

Journal ISSN

Technical informations

Creation

First validation

Update

Status update

Last indexation