Planar Chiral Arylaldehydeimine Tricarbonylchromium Complexes in the Asymmetric Baylis-Hillman Coupling Reaction

Kundig, Ernst Peter; Xu, Long He; Schnell, Barbara

doi:10.1055/s-1994-22869

Scientific article

English

Planar Chiral Arylaldehydeimine Tricarbonylchromium Complexes in the Asymmetric Baylis-Hillman Coupling Reaction

ContributorsKundig, Ernst Peter; Xu, Long He; Schnell, Barbara

Published inSynlett, no. 6, p. 413-414

Publication date1994

Abstract

The DABCO-catalyzed coupling reaction of methyl acrylate and acrylonitrile with enantiomerically pure planar chiral o-substituted (benzaldehyde tosylimine) Cr(CO)3 complexes after metal removal provides chiral amines in high yields and enantiomeric excess.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

KUNDIG, Ernst Peter, XU, Long He, SCHNELL, Barbara. Planar Chiral Arylaldehydeimine Tricarbonylchromium Complexes in the Asymmetric Baylis-Hillman Coupling Reaction. In: Synlett, 1994, n° 6, p. 413–414. doi: 10.1055/s-1994-22869

Identifiers

PID : unige:6196
DOI : 10.1055/s-1994-22869

Journal ISSN0936-5214

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Planar Chiral Arylaldehydeimine Tricarbonylchromium Complexes in the Asymmetric Baylis-Hillman Coupling Reaction

The DABCO-catalyzed coupling reaction of methyl acrylate and acrylonitrile with enantiomerically pure planar chiral o-substituted (benzaldehyde tosylimine) Cr(CO)3 complexes after metal removal provides chiral amines in high yields and enantiomeric excess.

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