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Reversibility of the Lithiation of η6 Naphthalenetricarbonylchromium

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Spichiger, Serge
Published in Journal of Organometallic Chemistry. 1987, vol. 332, no. 3, p. C13-C16
Abstract The lithiation of naphthalenetricarbonylchromium with n-BuLi or tetramethylpiperidyllithium is under kinetic control, and with the latter reagent is highly regioselective in the 2-position. Addition of isopropylamine renders the process reversible, and an approximately 1/1 equilibrium mixture of 1- and 2-substitution product is formed.
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KUNDIG, Ernst Peter, GRIVET, Chantal, SPICHIGER, Serge. Reversibility of the Lithiation of η6 Naphthalenetricarbonylchromium. In: Journal of Organometallic Chemistry, 1987, vol. 332, n° 3, p. C13-C16. https://archive-ouverte.unige.ch/unige:6186

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Deposited on : 2010-04-20

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