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Enantioselective Organocatalyzed Conjugate Addition of Carbonyl Compounds to New Functionalized Nitroolefins and Applications in Gold-Catalyzed Reactions

Author
Belot, Sébastien
Director
Defense Thèse de doctorat : Univ. Genève, 2010 - Sc. 4194 - 2010/03/17
Abstract In the highly competitive field of organocatalysis, we thought about developing something new and original. Being inspired by the organocatalyzed addition of carbonyl compounds to β-nitrostyrene we investigated a new type of nucleophile (donor) and a new type of electrophiles (acceptors). Therefore, in this thesis research, a huge effort has been devoted to the development of useful adducts which could be further transformed into interesting building blocks of high molecular complexity. As a result, organocatalysis combined with another synthetic transformation appears to become a new powerful tool that could be used in total synthesis.
Keywords OrganocatalsyisGold catalysisConjugate addition
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URN: urn:nbn:ch:unige-57065
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BELOT, Sébastien. Enantioselective Organocatalyzed Conjugate Addition of Carbonyl Compounds to New Functionalized Nitroolefins and Applications in Gold-Catalyzed Reactions. Université de Genève. Thèse, 2010. https://archive-ouverte.unige.ch/unige:5706

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Deposited on : 2010-04-15

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