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Doctoral thesis
English

Enantioselective Organocatalyzed Conjugate Addition of Carbonyl Compounds to New Functionalized Nitroolefins and Applications in Gold-Catalyzed Reactions

ContributorsBelot, Sébastien
Defense date2010-03-17
Abstract

In the highly competitive field of organocatalysis, we thought about developing something new and original. Being inspired by the organocatalyzed addition of carbonyl compounds to β-nitrostyrene we investigated a new type of nucleophile (donor) and a new type of electrophiles (acceptors). Therefore, in this thesis research, a huge effort has been devoted to the development of useful adducts which could be further transformed into interesting building blocks of high molecular complexity. As a result, organocatalysis combined with another synthetic transformation appears to become a new powerful tool that could be used in total synthesis.

eng
Keywords
  • Organocatalsyis
  • Gold catalysis
  • Conjugate addition
Citation (ISO format)
BELOT, Sébastien. Enantioselective Organocatalyzed Conjugate Addition of Carbonyl Compounds to New Functionalized Nitroolefins and Applications in Gold-Catalyzed Reactions. 2010. doi: 10.13097/archive-ouverte/unige:5706
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Creation03/23/2010 3:44:00 PM
First validation03/23/2010 3:44:00 PM
Update time03/14/2023 3:26:15 PM
Status update03/14/2023 3:26:15 PM
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