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Title

Copper-Catalysed Ring Opening of Polycyclic meso-Hydrazines with Trialkylaluminium Reagents and SimplePhos Ligands

Authors
Bournaud, Chloée
Micouin, Laurent
Published in Chemistry - A European Journal. 2010, vol. 16, no. 8, p. 2567-2573
Abstract meso-Hydrazines could be desymmetrised by ring-opening reactions by using various metal catalysts to form substituted cyclopentenes, which have a high synthetic potential. Herein, we report the asymmetric copper-catalysed ring opening of a range of polycyclic hydrazines with trialkylaluminium reagents and SimplePhos ligands with both high isolated yields and enantioselectivities of up to 95 %.
Keywords AluminumCopperDesymmetrizationHydrazinesP ligands
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PALAIS, Laetitia et al. Copper-Catalysed Ring Opening of Polycyclic meso-Hydrazines with Trialkylaluminium Reagents and SimplePhos Ligands. In: Chemistry - A European Journal, 2010, vol. 16, n° 8, p. 2567-2573. https://archive-ouverte.unige.ch/unige:5287

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Deposited on : 2010-03-01

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