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Synthesis, structure and dehydrogenation of zirconium borohydride octaammoniate

Published inChemical communications, vol. 51, no. 14, p. 2794-2797
Publication date2015
Abstract

A new metal borohydride ammoniate (MBA), Zr(BH4)4·8NH3, was synthesized via ammoniation of the Zr(BH4)4 crystal. Zr(BH4)4·8NH3 has a distinctive structure and the highest coordination number of NH3 groups among all the known MBAs. This compound could quickly dehydrogenate at 130 °C, enabling it a potential hydrogen storage material.

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Citation (ISO format)
HUANG, Jianmei et al. Synthesis, structure and dehydrogenation of zirconium borohydride octaammoniate. In: Chemical communications, 2015, vol. 51, n° 14, p. 2794–2797. doi: 10.1039/C4CC09317H
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ISSN of the journal1359-7345
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Creation03/03/2015 4:05:00 PM
First validation03/03/2015 4:05:00 PM
Update time03/14/2023 11:01:14 PM
Status update03/14/2023 11:01:14 PM
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