Synthesis, structure and dehydrogenation of zirconium borohydride octaammoniate

Huang, Jianmei; Tan, Yingbin; Su, Jiahao; Gu, Qinfen; Cerny, Radovan; Ouyang, Liuzhang; Sun, Dalin; Yu, Xuebin; Zhu, Min

doi:10.1039/C4CC09317H

Scientific article

English

Synthesis, structure and dehydrogenation of zirconium borohydride octaammoniate

ContributorsHuang, Jianmei; Tan, Yingbin; Su, Jiahao; Gu, Qinfen; Cerny, Radovan; Ouyang, Liuzhang; Sun, Dalin; Yu, Xuebin; Zhu, Min

Published inChemical communications, vol. 51, no. 14, p. 2794-2797

Publication date2015

Abstract

A new metal borohydride ammoniate (MBA), Zr(BH4)4·8NH3, was synthesized via ammoniation of the Zr(BH4)4 crystal. Zr(BH4)4·8NH3 has a distinctive structure and the highest coordination number of NH3 groups among all the known MBAs. This compound could quickly dehydrogenate at 130 °C, enabling it a potential hydrogen storage material.

Affiliation entities

Faculté des sciences / Section de physique / Département de physique de la matière quantique

Research groups

Groupe Cerny

Citation (ISO format)

HUANG, Jianmei et al. Synthesis, structure and dehydrogenation of zirconium borohydride octaammoniate. In: Chemical communications, 2015, vol. 51, n° 14, p. 2794–2797. doi: 10.1039/C4CC09317H

Article (Published version)

Identifiers

PID : unige:48129
DOI : 10.1039/C4CC09317H

Commercial URLhttp://xlink.rsc.org/?DOI=C4CC09317H

Journal ISSN1359-7345

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Creation03/03/2015 17:05:00

First validation03/03/2015 17:05:00

Update time15/03/2023 00:01:14

Status update15/03/2023 00:01:14

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Synthesis, structure and dehydrogenation of zirconium borohydride octaammoniate

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