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Synthesis, structure and dehydrogenation of zirconium borohydride octaammoniate

Huang, Jianmei
Tan, Yingbin
Su, Jiahao
Gu, Qinfen
Ouyang, Liuzhang
Sun, Dalin
Yu, Xuebin
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Published in Chemical Communications. 2015, vol. 51, no. 14, p. 2794-2797
Abstract A new metal borohydride ammoniate (MBA), Zr(BH4)4·8NH3, was synthesized via ammoniation of the Zr(BH4)4 crystal. Zr(BH4)4·8NH3 has a distinctive structure and the highest coordination number of NH3 groups among all the known MBAs. This compound could quickly dehydrogenate at 130 °C, enabling it a potential hydrogen storage material.
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Other version: http://xlink.rsc.org/?DOI=C4CC09317H
Research group Groupe Cerny
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HUANG, Jianmei et al. Synthesis, structure and dehydrogenation of zirconium borohydride octaammoniate. In: Chemical Communications, 2015, vol. 51, n° 14, p. 2794-2797. doi: 10.1039/C4CC09317H https://archive-ouverte.unige.ch/unige:48129

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Deposited on : 2015-03-11

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