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Transition metal-free asymmetric and diastereoselective allylic alkylation using Grignard reagents: construction of vicinal stereogenic centers via kinetic resolution

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Published in Chemical Science. 2014, vol. 5, no. 10, p. 3803-3807
Abstract The first transition metal-free diastereoselective and enantioselective asymmetric allylic alkylation (AAA) has been disclosed leading to the construction of vicinal tertiary/quaternary centers via a kinetic resolution protocol starting from readily available starting materials. This procedure is chemically appealing since no consecutive AAA or stereoselective metal-catalyzed/chiral ligand AAAs are required to construct the two stereocenters.
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Other version: http://xlink.rsc.org/?DOI=C4SC01003E
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GRASSI, David, ALEXAKIS, Alexandre. Transition metal-free asymmetric and diastereoselective allylic alkylation using Grignard reagents: construction of vicinal stereogenic centers via kinetic resolution. In: Chemical Science, 2014, vol. 5, n° 10, p. 3803-3807. https://archive-ouverte.unige.ch/unige:41530

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Deposited on : 2014-11-04

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